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Synthesis, crystal structure, and porosity calculation of novel lanthanide coordination polymers involving naphthalene-1,4,5,8-tetra-carboxylate as ligand

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Abstract

Two isostructural microporous coordination polymers of 1,4,5,8-naphthalenetetracarboxylic acid (H4Ntc) with rare earth metals were obtained in gel diffusion method, with chemical formulae [Y2(Ntc)1.5(H2O)5] · 6H2O) (I) and [Er2(Ntc)1.5(H2O)5] · 6H2O (II). They crystallized in the monoclinic system, space group P21/c. The crystal structure study revealed two crystallographically independent La3+ ions, and two crystallographically independent ligands were in the structure of the compounds I and II. Their crystal structure were 3D and exhibited some large channels with rectangular sections spreading along the x axis. The porosity has been calculated using Connolly’s algorithm after the crystallization water molecules were formally removed.

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Authors and Affiliations

  1. The School of Chemical and Biological Engineering, University of Science and Technology Beijing, Beijing, 100083, P.R. China

    W. Tao, J. M. Liu, Y. J. Zheng & C. Y. Sun

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  1. W. Tao
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  2. J. M. Liu
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  3. Y. J. Zheng
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  4. C. Y. Sun
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Correspondence to J. M. Liu.

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Tao, W., Liu, J.M., Zheng, Y.J. et al. Synthesis, crystal structure, and porosity calculation of novel lanthanide coordination polymers involving naphthalene-1,4,5,8-tetra-carboxylate as ligand. Russ J Coord Chem 39, 544–548 (2013). https://doi.org/10.1134/S1070328413060109

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  • DOI: https://doi.org/10.1134/S1070328413060109

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