Skip to main content
SpringerLink
Log in

Host-guest supramolecular complexes of the composition [M{NH(CH2)4O}{S2CN(C2H5)2}2] · CHCl3 (M = Zn, 63Cu(II)): Synthesis, structure, spectral properties, and thermal behavior

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Solvated forms of adducts [M{NH(CH2)4O}{S2CN(C2H5)2}2] · CHCl3 (M = Zn (I), 63Cu (II)) are preparatively isolated. Nonequivalence of the dithiocarbamate groups in structure I is revealed by the 13C MAS NMR method. According to the X-ray analysis data, adduct I is a supramolecular compound, whose structure includes a system of ordered channels occupied by outer-sphere solvating guest molecules of CHCl3 (structural type of lattice clathrates). The solvation of the initial adduct is accompanied by the structural unification of its isomeric forms and an increase in the strength of binding of the morpholine molecules and in the contribution of the trigonal-bipyramidal component to the geometry of the zinc polyhedron. The character of triaxial anisotropy of the EPR parameters of isotopically substituted compound II in the magnetically dilute state is due to the geometry of the copper polyhedron, which is intermediate between a tetragonal pyramid and a trigonal bipyramid with the ground state of an unpaired electron formed by mixing of the \(3d_{x^2 - y^2 } \)- and \(3d_{z^2 } \)-atomic orbitals (AO) of copper(II). The thermal destruction of compound I studied by simultaneous thermal analysis includes stages of desorption of solvating chloroform molecules and coordinated morpholine molecules and thermolysis of the “dithiocarbamate part” of the adduct.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Larionov, S.V., Klevtsova, R.F., Zemskova, S.M., and Glinskaya, L.A., Khim. Interesah Ustoich. Razvit., 1999, vol. 7, no. 4, p. 451.

    CAS  Google Scholar 

  2. Ivanov, A.V., Mitrofanova, V.I., Kritikos, M., and Antzutkin, O.N., Polyhedron, 1999, vol. 18, no. 15, p. 2069.

    Article  CAS  Google Scholar 

  3. Ivanov, A.V. and Antzutkin, O.N., Polyhedron, 2002, vol. 21, nos 27–28, p. 2727.

    Article  CAS  Google Scholar 

  4. Decken, A., Eisnor, Ch.R., Gossage, R.A., and Jackson, S.M., Inorg. Chim. Acta, 2006, vol. 359, no. 6, p. 1743.

    Article  CAS  Google Scholar 

  5. Siddiqi, K.S., Nami, S.A.A., and Lutfullah Chebude, Y., J. Braz. Chem. Soc., 2006, vol. 17, no. 1, p. 107.

    Article  CAS  Google Scholar 

  6. Khan, S., Nami, S.A.A., and Siddiqi, K.S., J. Mol. Struct., 2008, vol. 875, nos 1–3, p. 478.

    Article  CAS  Google Scholar 

  7. Srinivasan, N., Thirumaran, S., and Ciattini, S., J. Mol. Struct., 2009, vol. 936, nos. 1–3, p. 234.

    Article  CAS  Google Scholar 

  8. Subha, P.V., Valarmathi, P., Srinivasan, N., et al., Polyhedron, 2010, vol. 29, no. 3, p. 1078.

    Article  CAS  Google Scholar 

  9. Onwudiwe, D.A., Ajibade, P.A., and Omondi, B., J. Mol. Struct., 2011, vol. 987, no. 1, p. 58.

    Article  CAS  Google Scholar 

  10. Ajibade, P.A., Onwudiwe, D.C., and Moloto, M.J., Polyhedron, 2011, vol. 30, no. 2, p. 246.

    Article  CAS  Google Scholar 

  11. Marx Nirmal, R., Pandian, K., and Sivakumar, K., Appl. Surf. Sci., 2011, vol. 257, no. 7, p. 2745.

    Article  CAS  Google Scholar 

  12. Rodina, T.A., Ivanov, A.V., Gerasimenko, A.V., et al., Inorg. Chim. Acta, 2011, vol. 368, no. 1, p. 263.

    Article  CAS  Google Scholar 

  13. Byr’ko, V.M., Ditiokarbamaty (Dithopcarbamates), Moscow: Nauka, 1984.

    Google Scholar 

  14. Larionov, S.V., Zh. Neorg. Khim., 1993, vol. 38, no. 10, p. 1616.

    Google Scholar 

  15. Ivanov, A.V., Forsling, W., Kritikos, M., et al., Dokl. Ross. Akad. Nauk, 1999, vol. 369, no. 1, p. 64.

    CAS  Google Scholar 

  16. Ivanov, A.V., Kritikos, M., Antzutkin, O.N., and Forsling, W., Inorg. Chim. Acta, 2001, vol. 321, nos. 1–2, p. 63.

    Article  CAS  Google Scholar 

  17. Ivanov, A.V., Lutsenko, I.A., Gerasimenko, A.V., and Merkulov, E.B., Russ. J. Inorg. Chem., 2008, vol. 53, no. 2, p. 293.

    Article  Google Scholar 

  18. Ivanov, A.V., Lutsenko, I.A., Zaeva, A.S., et al., Russ. J. Coord. Chem., 2007, vol. 33, no. 11, p. 815.

    Article  CAS  Google Scholar 

  19. Bonamico, M., Mazzone, G., Vaciago, A., and Zambonelli, L., Acta Crystallogr., 1965, vol. 19, no. 6, p. 898.

    Article  CAS  Google Scholar 

  20. Pines, A., Gibby, M.G., and Waugh, J.S., J. Chem. Phys., 1972, vol. 56, no. 4, p. 1776.

    Article  CAS  Google Scholar 

  21. Earl, W.L. and VanderHart D.L., J. Magn. Reson., 1982, vol. 48, no. 1, p. 35.

    CAS  Google Scholar 

  22. Morcombe, C.R. and Zilm, K.W., J. Magn. Reson., 2003, vol. 162, no. 2, p. 479.

    Article  CAS  Google Scholar 

  23. Farrugia, L.J., J. Appl. Crystallogr., 1999, vol. 32, no. 4, p. 837.

    Article  CAS  Google Scholar 

  24. North, A.C.T., Phillips, D.C., and Mathews, F.S., Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr., 1968, vol. 64, no. 3, p. 351.

    Article  Google Scholar 

  25. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.

    Article  Google Scholar 

  26. Ovchinnikov, I.V. and Konstantinov, V.N., J. Magn. Reson., 1978, vol. 32, no. 2, p. 179.

    CAS  Google Scholar 

  27. Rieger, Ph.H., Electron Spin Resonance/Senior Reporter Symons M.C.R., Newcastle upon Tyne: Athenaeum, 1993, vol. 13B, p. 178, p. 2976.

    Google Scholar 

  28. Arriortua, M.A., Mesa, J.L., Rojo, T., et al., Inorg. Chem., 1988, vol. 27, no. 17, p. 2976.

    Article  CAS  Google Scholar 

  29. Murakami, T., Takei, T., and Ishikawa, Y., Polyhedron, 1997, vol. 16, no. 1, p. 89.

    Article  CAS  Google Scholar 

  30. Ivanov, A.V., Forsling, W., Antzutkin, O.N., and Novikova, E.V., Russ. J. Coord. Chem., 2001, vol. 27, no. 3, p. 158.

    Article  CAS  Google Scholar 

  31. Ivanov, A.V., Kritikos, M., Antzutkin, O.N., et al., Russ. J. Coord. Chem., 1999, vol. 25, no. 8, p. 543.

    CAS  Google Scholar 

  32. Ivanov, A.V., Forsling, W., Antzutkin, O.N., et al., Dokl. Ross. Akad. Nauk, 1999, vol. 366, no. 5, p. 643.

    CAS  Google Scholar 

  33. Ivanov, A.V., Kritikos, M., Antzutkin, O.N., and Lund, A., Russ. J. Inorg. Chem., 1999, vol. 44, no. 10, p. 1605.

    Google Scholar 

  34. Lutsenko, I.A., Ivanov, A.V., Zaeva, A.S., and Gerasimenko, A.V., Russ. J. Coord. Chem., 2010, vol. 36, no. 7, p. 502.

    Article  CAS  Google Scholar 

  35. Ivanov, A.V. and Antzutkin, O.N., Topics Curr. Chem., 2005, vol. 246, p. 271.

    Article  CAS  Google Scholar 

  36. Ivanov, A.V., Rodina, T.A., and Antzutkin, O.N., Polyhedron, 1998, vol. 17, no. 18, p. 3101.

    Article  Google Scholar 

  37. Levy, G.C., Lichter, R.L., and Nelson, G.L., Carbon-13 Nuclear Magnetic Resonance Spectroscopy, New York: Wiley, 1980.

    Google Scholar 

  38. Pauling, L., The Nature of the Chemical Bond and the Structure of Molecules and Crystals, London: Cornell Univ., 1960.

    Google Scholar 

  39. Bondi, A., J. Phys. Chem., 1964, vol. 68, no. 3, p. 441.

    Article  CAS  Google Scholar 

  40. Bondi, A., J. Phys. Chem., 1966, vol. 70, no. 9, p. 3006.

    Article  CAS  Google Scholar 

  41. Steed, D.V. and Atwood, D.L., Supramolecular Chemistry, New York: Wiley, 2000, vol. 2.

    Google Scholar 

  42. Addison, A.W., Rao, T.N., Reedijk, J., et al., J. Chem. Soc., Dalton Trans., 1984, no. 7, p. 1349.

Download references

Author information

Authors and Affiliations

  1. Institute of Geology and Nature Management, Far Eastern Branch of the Russian Academy of Sciences, Blagoveschensk, 675000, Russia

    I. A. Lutsenko, A. V. Ivanov & E. V. Korneeva

  2. Moscow State University, Moscow, Russia

    A. I. Tursina

Authors
  1. I. A. Lutsenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Korneeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. I. Tursina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Ivanov.

Additional information

Original Russian Text © I.A. Lutsenko, A.V. Ivanov, E.V. Korneeva, A.I. Tursina, 2012, published in Koordinatsionnaya Khimiya, 2012, Vol. 38, No. 11, pp. 779–786.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lutsenko, I.A., Ivanov, A.V., Korneeva, E.V. et al. Host-guest supramolecular complexes of the composition [M{NH(CH2)4O}{S2CN(C2H5)2}2] · CHCl3 (M = Zn, 63Cu(II)): Synthesis, structure, spectral properties, and thermal behavior. Russ J Coord Chem 38, 709–716 (2012). https://doi.org/10.1134/S1070328412100090

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328412100090

Keywords

Search

Navigation