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Synthesis, crystal structure, and luminescent property of [Zn2(Ox)3]H2L · 4H2O (L = 2,2′-(1,4-butanediyl-bis(1H-benzimidazole))

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Abstract

A new complex [Zn2(Ox)3]H2L · 4H2O (L = 2,2′-(1,4-butanediyl)-bis(1H-benzimidazole)) (I) has been hydrothermally synthesized and characterized by the elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. It crystallizes in monoclinic space group P21/c with a = 10.108(2), b = 15.600(4), c = 9.768(2) Å, β = 105.289(3)·, V = 1485.7(6) Å3, Z = 4. Complex I is a 2D honeycomb-like polymer with pro-toned L and water molecules intercalating in the cavities. The luminescent spectra shows the emission peak of complex I is at 455 nm which is attributed to ligand-to-metal charge transfer.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Chang’an University, Xi’an, Shaanxi, 710061, P.R. China

    L. Gou, H. X. Zhang, X. Y. Fan & D. L. Li

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  1. L. Gou
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  2. H. X. Zhang
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  3. X. Y. Fan
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  4. D. L. Li
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Correspondence to L. Gou.

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Gou, L., Zhang, H.X., Fan, X.Y. et al. Synthesis, crystal structure, and luminescent property of [Zn2(Ox)3]H2L · 4H2O (L = 2,2′-(1,4-butanediyl-bis(1H-benzimidazole)). Russ J Coord Chem 38, 609–613 (2012). https://doi.org/10.1134/S1070328412080052

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  • DOI: https://doi.org/10.1134/S1070328412080052

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