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Crystal structure of copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide

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Abstract

X-Ray diffraction analysis was performed for the copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide, Cu(p-(tert-Bu)C6H4CONHNMe2)2 (I). The reagent functions as a bidentate (O,N(2)) ligand giving a five-membered copper-containing ring. The molecule is centrosymmetric. The Cu atom and the metal rings lie in the same plane. The coordination polyhedron of copper is a slightly distorted square. The crystals are monoclinic: a = 16.2634(14) Å, b = 9.0415(8) Å, c = 9.6415(9) Å, α = 90°, β = 100.052(7)°, Z = 2, space group P21/c.

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Authors and Affiliations

  1. Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences, ul Lenina 13, Perm, 614600, Russia

    V. Yu. Gusev, D. A. Muksinova & A. V. Radushev

  2. Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    P. A. Slepukhin

Authors
  1. V. Yu. Gusev
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  2. D. A. Muksinova
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  3. P. A. Slepukhin
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  4. A. V. Radushev
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Correspondence to V. Yu. Gusev.

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Original Russian Text © V.Yu. Gusev, D.A. Muksinova, P.A. Slepukhin, A.V. Radushev, 2012, published in Koordinatsionnaya Khimiya, 2012, Vol. 38, No. 8, pp. 547–550.

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Gusev, V.Y., Muksinova, D.A., Slepukhin, P.A. et al. Crystal structure of copper(II) chelate with para-(tert-butyl)benzoic acid N′,N′-dimethylhydrazide. Russ J Coord Chem 38, 515–518 (2012). https://doi.org/10.1134/S1070328412070044

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  • DOI: https://doi.org/10.1134/S1070328412070044

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