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Tris(2-methoxy-5-bromophenyl)antimony bis(2-nitrobenzoate): Synthesis and specific features of the structure

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Abstract

Tris(5-bromo-2-methoxyphenyl)antimony bis(2-nitrobenzoate) (I) is synthesized by the reaction of tris(5-bromo-2-methoxyphenyl)antimony with 2-nitrobenzoic acid in the presence of hydrogen peroxide (mole ratio 1: 2: 1). According to the X-ray diffraction data, the antimony atom has distorted trigonal bipyramidal coordination. The axial angle OSbO is 177.92(11)°, equatorial bonds CSbC are 109.23(16)°–128.31(16)°, and the Sb-O and Sb-C bond lengths are 2.095(3)–2.125(3) and 2.098(4)–2.113(4) Å, respectively. A specific feature of the structure of complex I is the presence of intramolecular contacts Sb...O(CH3) (2.992–3.175 Å along with the interactions Sb...O=C (3.039–3.117 Å). The structural organization in crystal is due to weak hydrogen bonds N-O...H-C, C=O...H-C, C-Br...H-C.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, V. S. Senchurin, O. K. Sharutina, O. V. Chagarova & L. E. Zelevets

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  1. V. V. Sharutin
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  2. V. S. Senchurin
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  3. O. K. Sharutina
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  4. O. V. Chagarova
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  5. L. E. Zelevets
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, V.S. Senchurin, O.K. Sharutina, O.V. Chagarova, L.E. Zelevets, 2011, published in Koordinatsionnaya Khimiya, 2011, Vol. 37, No. 10, pp. 782–785.

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Sharutin, V.V., Senchurin, V.S., Sharutina, O.K. et al. Tris(2-methoxy-5-bromophenyl)antimony bis(2-nitrobenzoate): Synthesis and specific features of the structure. Russ J Coord Chem 37, 781–784 (2011). https://doi.org/10.1134/S1070328411090089

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  • DOI: https://doi.org/10.1134/S1070328411090089

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