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Organic-inorganic hybrid supramolecular architecture constructed from Keggin-type [PMo12O40]3− clusters and transition metal complexes

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Abstract

A Keggin organic-inorganic hybrid polyoxometalate combined with nickel complex [Ni (Dmf)3(H2O)][HPMo12O40] · (Dmf) · 2H2O (I) has been synthesized and structurally characterized by elemental analysis, IR spectrum, TG analysis, cyclic voltammetry, and single-crystal X-ray diffraction. Interestingly, a two-dimensional supramolecular network is constructed by the [PMo12O40]3− polyanions, [Ni(Dmf)3(H2O)]2+ cations, and water molecules via hydrogen-bonding interactions. The cyclic voltammetric measurements illustrate that the [PMo12O40]3− polyanion is the electrochemical redox active center of I in the solution.

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Authors and Affiliations

  1. Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, P.R. China

    J. W. Zhao, X. F. Zhang, P. T. Ma, Y. Q. Feng, J. P. Wang & J. Y. Niu

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  1. J. W. Zhao
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  2. X. F. Zhang
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  3. P. T. Ma
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  4. Y. Q. Feng
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  5. J. P. Wang
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  6. J. Y. Niu
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Correspondence to J. Y. Niu.

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Zhao, J.W., Zhang, X.F., Ma, P.T. et al. Organic-inorganic hybrid supramolecular architecture constructed from Keggin-type [PMo12O40]3− clusters and transition metal complexes. Russ J Coord Chem 35, 891–895 (2009). https://doi.org/10.1134/S1070328409120057

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  • DOI: https://doi.org/10.1134/S1070328409120057

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