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An ion crystal based on silver double helicates and Keggin polyanions

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Abstract

An ion crystal [Ag2L2][(n-C4H9)4N][PMo12O40] · H2O · 0.5CH3OH · 0.25 DMF (I) (DMF is N,N-dimethylformamide) has been synthesized by the complexation of metal double helix and Keggin polyanions in a DMF-CH3 OH solution and structurally characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. In compound I [PMo12O40]3− anions and [(n-C4H9)4N]+ ions alternately arrange themselves in a special order in consistence with that of [Ag2L2]2+ metal helicates based on π-π stacking interactions, yielding a packing of complex cations and Keggin anions.

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References

  1. Uchida, S. and Mizuno, N., Chem. Eur. J., 2003, vol. 9, p. 5850.

    Article  CAS  Google Scholar 

  2. Kawamoto, R., Uchida, S., and Mizuno, N., J. Am. Chem. Soc., 2005, vol. 127, p. 10560.

    Article  CAS  Google Scholar 

  3. Jiang, C., Lesbani, A., Kawamoto, R., et al., J. Am. Chem. Soc., 2006, vol. 127, p. 14240.

    Article  Google Scholar 

  4. Kong, X.J., Ren, Y.P., Zheng, P.Q., et al., Inorg. Chem., 2006, vol. 45, p. 10702.

    Article  CAS  Google Scholar 

  5. Wei, M.L., He, C., Sun, Q.Z., et al., Inorg. Chem., 2007, vol. 46, p. 5957.

    Article  CAS  Google Scholar 

  6. Albrecht, M., Chem. Rev., 2001, vol. 101, p. 3457.

    Article  CAS  Google Scholar 

  7. Kitagawa, S., Kitaura, R., and Noro, S.I., Angew. Chem. Int. Ed., 2004, vol. 43, p. 2334.

    Article  CAS  Google Scholar 

  8. Anthony, S.P. and Radhakrishnan, T.P., Chem. Commun., 2004, p. 1058.

  9. Siemeling, U., Scheppelmann, I., Neumann, B., et al., Chem. Commun., 2003, p. 2236.

  10. Lu, W.G., Jiang, L., Feng, X.L., et al., Cryst. Growth Des., 2008, vol. 8, no. 3, p. 986.

    Article  CAS  Google Scholar 

  11. Sun, Q.Z., Bai, Y., He, G.J., et al., Chem. Commun., 2006, p. 2777.

  12. Azumaya, I., Uchida, D., Kato, T., et al., Angew. Chem. Int. Ed., 2004, vol. 43, p. 1360.

    Article  CAS  Google Scholar 

  13. Childs, L.J., Pascu, M., Clarke, A.J., et al., Chem. Eur. J., 2004, vol. 10, p. 4291.

    Article  CAS  Google Scholar 

  14. Childs, L.J., Alcock, N.W., and Hannon, M.J., Angew. Chem., 2001, vol. 113, p. 1113.

    Article  Google Scholar 

  15. Oh, M., Carpenter, G., and Sweigart, D.A., Acc. Chem. Res., 2004, vol. 37, p. 1.

    Article  CAS  Google Scholar 

  16. Sanchez, C., Livage, J., Launay, J.P., et al., J. Am. Chem. Soc., 1982, vol. 104, no. 11, p. 3194.

    Article  CAS  Google Scholar 

  17. SMART and SAINT, Area Detector Control and Integration Software, Madison (WI, USA): Siemens Analytical X-Ray Systems, Inc., 1996.

  18. Sheldrick, G.M., SHELXTL, Version 5.1, Software Reference Manual, Madison (WI, USA): Bruker AXS, Inc., 1997.

    Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Environmental Science, Henan Normal University, Xinxiang, 453007, P.R. China

    M. L. Wei, R. P. Sun, P. F. Zhuang & Y. H. Yang

Authors
  1. M. L. Wei
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  2. R. P. Sun
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  3. P. F. Zhuang
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  4. Y. H. Yang
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Correspondence to M. L. Wei.

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Wei, M.L., Sun, R.P., Zhuang, P.F. et al. An ion crystal based on silver double helicates and Keggin polyanions. Russ J Coord Chem 35, 885–890 (2009). https://doi.org/10.1134/S1070328409120045

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  • DOI: https://doi.org/10.1134/S1070328409120045

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