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Layered coordination polymer of silver methanesulfonate with 2,3,5,6-tetramethylpyrazine

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Abstract

The complex [Ag2(Me4-Pyz)(CH3SO3)2]·2H2O is synthesized, and its structure is determined. The crystals are monoclinic, space group P21 /n,a = 11.821(1), b = 4.906(1), c = 15.782(1) Å,β = 94.34(1) °, V = 912.5(2) Å3, ρ(calcd) = 2.104 g/cm3, Z = 2. The Ag+ ion is coordinated at the vertices of the distorted tetrahedron by the nitrogen atom of tetramethylpyrazine and three oxygen atoms of two methanesulfonate ions (Ag(1)-N(1) 2.283(2), Ag (1)-O(RSO −3 )2.386(3)-2.451(2) Å, angles at the Ag atom 86.8(1)°–129.1(1)°). The structure contains layers of sulfonate-silver chains and tetramethylpyrazine molecules extended along the direction [101].

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    Yu. V. Kokunov, Yu. E. Gorbunova & G. A. Razgonyaeva

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  1. Yu. V. Kokunov
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  2. Yu. E. Gorbunova
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  3. G. A. Razgonyaeva
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Correspondence to Yu. V. Kokunov.

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Original Russian Text © Yu.V. Kokunov, Yu.E. Gorbunova, G.A. Razgonyaeva, 2009, published in Koordinatsionnaya Khimiya, 2009, Vol. 35, No. 12, pp. 891–896.

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Kokunov, Y.V., Gorbunova, Y.E. & Razgonyaeva, G.A. Layered coordination polymer of silver methanesulfonate with 2,3,5,6-tetramethylpyrazine. Russ J Coord Chem 35, 879–884 (2009). https://doi.org/10.1134/S1070328409120033

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  • DOI: https://doi.org/10.1134/S1070328409120033

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