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A novel azide copper complex: [[Azido{bis[2-(piperidin-1-ylmethyl)pyridine]}copper(II)]perchlorate] hydrate

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Abstract

Synthesis and single crystal X-ray diffraction study were carried for compound {[Cu(C11H16N4)2(N3)](ClO4)} · H2O (I). The structure is molecular, and the Cu2+ ion is in a five-coordinated compressed trigonal bipyramid environment. Copper ion is bound to five N atoms, in which four N atoms are from two chlelating ligands 2-(piperidin-1-ylmethyl)pyridine and the fifth N donor is from a monodentate azido ligand. The complex cations [Cu(C11H16N4)2(N3)]+, the perchlorate anions, and solvent water molecules are further joined into three dimensional supramolecular networks by rich hydrogen bonds including strong O-H…N between solvent water and azide ion and O-H…O between solvent water and perchlorate ion, and weak hydrogen bonds C-H…O, and weak bifurcated hydrogen bonds C-H/C-H…N in which N atom of azide ion serving as bifurcated acceptor and two C-H groups as donors.

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References

  1. Schubert, U.S. and Eschbaumer, C., Angew. Chem. Int. Ed., 2002, vol. 41, p. 2892.

    Article  CAS  Google Scholar 

  2. Zhou, M. and Roovers, J., Macromolecules, 2001, vol. 34, p. 244.

    Article  CAS  Google Scholar 

  3. Oh, M. and Mirkin, C.A., Nature, 2005, vol. 438, p. 651.

    Article  CAS  Google Scholar 

  4. Oh, M. and Mirkin, C.A., Angew. Chem. Int. Ed., 2006, vol. 45, p. 5492.

    Article  CAS  Google Scholar 

  5. Rakitin, Y.V. and Kalinnikov, V.T., Russ. Chem. Bull. Int. Ed., 2004, vol. 53, p. 766.

    Article  CAS  Google Scholar 

  6. Halcrow, M.A., Huffman, J.C., and Christou, G., Angew. Chem. Int. Ed., 1995, vol. 8, p. 889.

    Google Scholar 

  7. Ribas, J., Escuer, A., Monfort, M., et al., Coord. Chem. Rev., 1999, vol. 193–195, p. 1027.

    Article  Google Scholar 

  8. Bai, S.Q., Fang, C.J., and Yan, C.H., Chin. J. Inorg. Chem., 2006, vol. 12, p. 2123.

    Google Scholar 

  9. Sheldrick G.M., SHELX-97, Release 97-1, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  10. Aronica, C., Jeanneau, E., El Moll, H., et al., Chem. Eur. J., 2007, vol. 13, p. 3666.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. School of Pharmaceutical and Chemical Engineering, Taizhou University, Linhai, Zhejiang, 317000, P.R. China

    C. F. Wang, Z. L. Zhang, Y. L. Wang & G. L. Dai

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  1. C. F. Wang
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  2. Z. L. Zhang
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  3. Y. L. Wang
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  4. G. L. Dai
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Correspondence to C. F. Wang.

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Wang, C.F., Zhang, Z.L., Wang, Y.L. et al. A novel azide copper complex: [[Azido{bis[2-(piperidin-1-ylmethyl)pyridine]}copper(II)]perchlorate] hydrate. Russ J Coord Chem 35, 789–792 (2009). https://doi.org/10.1134/S1070328409100145

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  • DOI: https://doi.org/10.1134/S1070328409100145

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