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Two novel sandwich copper(II) complexes [CuLCl]2[CuCL4] and [CuLBr]2[CuBr4] (L = N,N′-bis(furaldehyde)diethylenetriamine)

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Abstract

The novel trinuclear copper(II) complexes [CuLCl]2[CuCl4](I) and [CuLBr]2[CuBr4] (II) (where L = N,N′-bis(furaldehyde) diethylenetriamine) were synthesized and structurally characterized by X-ray diffraction. They consist of sandwich units. Both I and II crystallize isomorphously in the monoclinic space group P2/n and feature cation/anion/cation geometry. The novel trinuclear copper(II) complexes I and II shown to be stabilized by a number of weak hydrogen bonds and intermolecular π-π stacking interactions.

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Authors and Affiliations

  1. Department of Chemical engineering, College of Environment and Engineering, Chang’an University, Xi’an, 710054, P.R. China

    W. Wang

  2. Department of Chemistry, Northwest University/Shaanxi province Key Laboratory of Physicoinorganic Chemistry, Xi’an, 710069, P.R. China

    W. Wang, F. X. Zhang, J. Li & W. B. Hu

Authors
  1. W. Wang
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  2. F. X. Zhang
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  3. J. Li
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  4. W. B. Hu
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Correspondence to W. Wang.

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Wang, W., Zhang, F.X., Li, J. et al. Two novel sandwich copper(II) complexes [CuLCl]2[CuCL4] and [CuLBr]2[CuBr4] (L = N,N′-bis(furaldehyde)diethylenetriamine). Russ J Coord Chem 35, 429–432 (2009). https://doi.org/10.1134/S1070328409060074

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  • DOI: https://doi.org/10.1134/S1070328409060074

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