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Tetragonal cubanoid Cu4X4 in the isostructural π-complexes with divinyltetramethyldisiloxane: [Cu4X4(C8H18OSi2) (X = Cl, Br)

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Abstract

The formation of the heterocubanoid fragmen Cu4Y4(Y = Cl, Br, I, O, S) in the structure of the Cu(I) complexes is often associated with the appearance of valuable properties (catalytic, thermal, chemiluminescence, and others) of these compounds. The Cu4X4 cluster (X = Cl, Br) found in the isostructural π-complexes with divinyltetramethyldisiloxane (DVTMSO) (space group P \( \bar 4 \), Z = 1, a = 10.2330(2) Å, c = 7.6877(3) Å for [Cu4Cl4(DVTMSO)2] and a = 10.2633(1) Å, c = 7.9514(3) Å for [Cu4Br4(DVTMSO)2]) makes it possible to discuss the homological chain of the Cu4X4 cuprohalide fragments from the viewpoint of steric (conformational, symmetric) and electronic (d Cu → π*(C=C)) properties of an organic ligand.

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Authors and Affiliations

  1. Institute of Chemistry, University of Opole, Opole, Poland

    T. Dużak, V. V. Olijnyk, B. Zarychta & J. Zaleski

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  1. T. Dużak
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  2. V. V. Olijnyk
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  3. B. Zarychta
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  4. J. Zaleski
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Correspondence to V. V. Olijnyk.

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Original Russian Text © T. Dużak, V.V. Olijnyk, B. Zarychta, J. Zaleski, 2009, published in Koordinatsionnaya Khimiya, 2009, vol. 35, No. 6, pp. 425–430.

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Dużak, T., Olijnyk, V.V., Zarychta, B. et al. Tetragonal cubanoid Cu4X4 in the isostructural π-complexes with divinyltetramethyldisiloxane: [Cu4X4(C8H18OSi2) (X = Cl, Br). Russ J Coord Chem 35, 416–421 (2009). https://doi.org/10.1134/S1070328409060050

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  • DOI: https://doi.org/10.1134/S1070328409060050

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