Skip to main content
Log in

Synthesis, characterization, and biological study of some biologically potent schiff base transition metal complexes

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The synthesis and characterization of a Schiff base derived from aniline and salicylaldehyde and its Co(II), Mn(II), and Zn(II) complexes is reported; several physical tools, in particular, elemental analysis, infrared and NMR techniques were used to investigate the chemical structure of the reported complexes. The ligand is found to be bound to the metal atom through the oxygen atom of the hydroxyl group, which is also supported by spectroscopic techniques. The results obtained by FT-IR and NMR showed that the Schiff base-transition metal complexes have octa hedral geometry. Biological screening of the complexes reveals that the Schiff base-transition metal complexes show significant activity against all microorganisms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Albertin, G., Bordignon, E., and Orio, A.A., Inorg. Chem., 1975, vol. 14, p. 1411.

    Article  CAS  Google Scholar 

  2. Karlin, K.D. and Zubieta, J (Eds), Copper Coordination Chemistry: Biochemical and Inorganic Perspectives, New York: Adenine Press, 1983, p. 43.

    Google Scholar 

  3. Holm, R.H., Everett, G.W., and Chakravorty, A., Prog. Inorg. Chem., 1966, vol. 7, p. 83.

    Article  CAS  Google Scholar 

  4. Kawakami, K., Miya-Uchi, M., and Tanaka, T., J. Inorg. Nuc. Chem., 1971, vol. 33, p. 3773.

    Article  CAS  Google Scholar 

  5. Bullock, J.I. and Tajmir-Riahi, H.A., Dalton Trans., 1978, p. 36.

  6. Bamfield, P., J. Chem. Soc., 1967, A, p. 804.

    Google Scholar 

  7. Mahmoud, M.R. and El-Haty, M.T., J. Inorg. Nucl. Chem., 1980, vol. 42, p. 349.

    Article  CAS  Google Scholar 

  8. Reilley, C.N., Schimid R.W., and Sadek F.A., J. Chem. Educ., 1959, vol. 36, p. 555.

    Article  CAS  Google Scholar 

  9. Rehman, W., Baloch, M.K., Badshah, A., and Ali S., J. Chin. Chem. Soc., 2005, vol. 52, 231.

    CAS  Google Scholar 

  10. Rehman, W., Badshah, A., Baloch, M.K., et al. J. Chin. Chem. Soc., 2004, vol. 51, p. 929.

    CAS  Google Scholar 

  11. Rehman, W., Baloch, M.K., Muhammad, B., et al. Chin. Sci. Bull., 2004, vol. 49, p. 119.

    Article  CAS  Google Scholar 

  12. Rehman, W., Baloch, M.K., Badshah, A., et al. Spectrochim. Acta A., 2006, vol. 65, p. 689.

    Article  CAS  Google Scholar 

  13. Rehman, W., Baloch, M.K., and Badshah, A., J. Braz. Chem. Soc., 2005, vol. 16, p. 827.

    Article  CAS  Google Scholar 

  14. Rehman, W., Baloch, M.K., Badshah, A., et al. Russ. J. Coord. Chem., 2005, vol. 31, p. 856.

    Article  CAS  Google Scholar 

  15. Rehman, W., Baloch, M.K., and Badshah, A., Russ. J. Inorg. Chem., 2007, vol. 52, p. 140.

    Article  Google Scholar 

  16. Chauhan, J.B., Subramanian, R.B., and Sanyal, P.K., Indian J. Environ. Toxicol., 2002, vol. 12, p. 22.

    Google Scholar 

  17. Tweedy, B.G., Phytopatology, 1964, vol. 55, p. 910.

    Google Scholar 

  18. Rahman, A., Choudhary, M.I., and Thomsen, W.J., Bioassay Techniques for Drug Development, Amsterdam (The Netherlands): Harwood Academic Publishers, 2001.

    Google Scholar 

  19. Rodriguez-Arguelles, M., Ferrari, M.B., Fava, G.G. et al. J. Inorg. Biochem. 1997, vol. 66, p. 7.

    Article  CAS  Google Scholar 

  20. Lima, L., Teixe Ira, L.R., Carneiro, T.G., et al., J. Braz. Chem. Soc., 1999,vol. 10, p.184.

    Google Scholar 

  21. Alderighia, L., Gans P., Ienco, A., et al. Coord. Chem. Rev., 1999, vol. 184, p. 311.

    Article  Google Scholar 

  22. Seeger, D.M., Korzeniewski, C., and Kowalchyk, W., J. Phys. Chem. 1991, vol. 95, p. 68.

    Article  Google Scholar 

  23. Golcu, A., Tumer, M., Demirelli, H., and Wheatley, R,A., Inorg. Chim. Acta., 2005, vol. 358, p. 1785.

    Article  CAS  Google Scholar 

  24. Doine, H., Bull. Chem. Soc. Jpn. 1985, vol. 58, p. 1327.

    Article  CAS  Google Scholar 

  25. Lewinski, J., Justyniak, I., Zachara, J., and Tratkiewicz, E., Organometallics, 2003, vol. 22. p. 4151.

    Article  CAS  Google Scholar 

  26. Lawrance, P.G., Harold, P.L., and Francis, O.G., Antibiotic Chemotheraphy, 1980, vol. 5, p. 1597.

    Google Scholar 

  27. Rich, S. and Horsfall, J.G., Phytopathology, 1952, vol. 42, p. 457.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to W. Rehman.

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rehman, W., Saman, F. & Ahmad, I. Synthesis, characterization, and biological study of some biologically potent schiff base transition metal complexes. Russ J Coord Chem 34, 678–682 (2008). https://doi.org/10.1134/S107032840809008X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032840809008X

Keywords

Navigation