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Functional self-assembly of hydrogen-bonded 3D coordination networks constructed from 1,2,4,5-benzenetetracarboxylic acid

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Abstract

Hydrothermal synthesis, characterization (IR, TG/DTA, element analysis, inductively coupled plasma (ICP)) and single-crystal X-ray structures of H4Btec hydrate and its two cobalt complexes, colorless [H4Btec · 2H2O] n (I), pink [Co(H2O)6(H2Btec)] n (II), and nacarat {[Co(H2O)3(H2Btec)(Phen)] · H2O} n (III) (H4Btec = 1,2,4,5-benzenetetracarboxylic acid, Phen = 1,10-phenanthroline) have been solved. The results showed that I forms a 3D O-H⋯O hydrogen-bonded network generated from H4Btec and water molecules, II presents a 3D network constructed by mononuclear [Co(H2O)6]2+ cations and H2Btec2− dianions through extensive hydrogen-bonding interactions, and III gives rise to a pseudo-octahedral coordination geometry. Extensive hydrogen-bonding interactions have significant effects in configuring a 3D network constructed by mononuclear [Co(H2Btec)(Phen)(H2O)3] neutral molecules and a water molecules.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Engineering, Jinan University, Jinan, Shandong, 250022, P. R. China

    Q. B. Bo, S. Y. Zhao, Z. W. Zhang, Y. L. Sheng, Z. X. Sun, G. X. Sun, C. L. Chen & Y. X. Li

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  1. Q. B. Bo
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  2. S. Y. Zhao
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  3. Z. W. Zhang
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  4. Y. L. Sheng
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  5. Z. X. Sun
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  6. G. X. Sun
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  7. C. L. Chen
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  8. Y. X. Li
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The article was submitted by the authors in English.

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Bo, Q.B., Zhao, S.Y., Zhang, Z.W. et al. Functional self-assembly of hydrogen-bonded 3D coordination networks constructed from 1,2,4,5-benzenetetracarboxylic acid. Russ J Coord Chem 33, 471–481 (2007). https://doi.org/10.1134/S1070328407070019

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  • DOI: https://doi.org/10.1134/S1070328407070019

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