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First examples of cyano-bridged complexes based on a novel cluster anion [Re12C17(CN)6]6−

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Abstract

Two cyano-bridged compounds of novel dodecanuclear cluster anion [Re12CS17(CN)6] with Ni2+ cations were synthesized, namely, one-dimensional polymer of the composition [{Ni(NH3)4} {Ni(NH3)5}2Re12CS17(CN)6] · 7H2O (I) with a chain structure and [Ni(NH3)6]3[{Ni(NH3)4}3 {Re12CS17(CN)6}2] · 21H2O (II), containing the anionic dimeric complex [{Ni(NH3)4}3 {Re12CS17(CN)6}2]6−. The structures of both compounds were established by X-ray diffraction analysis. Crystals I are monoclinic, space group P2/n, a = 15.321(3), b = 12.635(2), c = 15.448(3) Å, β = 100.242(3)°, V = 2942.8(8) Å3, Z = 2. Crystals II are trigonal, space group R3, a = b = 19.7987(14), c = 28.8642(18) Å, V = 9798.6(12) Å3, Z = 3.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akad. Lavrent’eva 3, Novosibirsk, 630090, Russia

    Yu. V. Mironov, N. G. Naumov & V. E. Fedorov

  2. Department of Chemistry, Ewha Womans University, Seoul, Korea

    Yu. V. Mironov, N. G. Naumov & Sung-Jin Kim

Authors
  1. Yu. V. Mironov
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  2. N. G. Naumov
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  3. Sung-Jin Kim
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  4. V. E. Fedorov
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Additional information

Original Russian Text © Yu.V. Mironov, N.G. Naumov, Sung-Jin Kim, V.E. Fedorov, 2007, published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 4, pp. 289–295.

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Mironov, Y.V., Naumov, N.G., Kim, SJ. et al. First examples of cyano-bridged complexes based on a novel cluster anion [Re12C17(CN)6]6− . Russ J Coord Chem 33, 279–285 (2007). https://doi.org/10.1134/S1070328407040070

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  • DOI: https://doi.org/10.1134/S1070328407040070

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