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The study of induced aquation of Rh(III) sulfate complexes

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Abstract

The processes of aquation of Rh(III) complexes in the presence of BaCl2 and Ba(ClO4)2 were studied by the 103RH and 17O NMR methods. In the first case, the final products were found to be the monomeric aqua chloride complexes, while in the second case, aqua hydroxo complexes were formed. The chloride ions present in the system significantly increase the process rate.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    S. N. Shagabutdinova & A. V. Belyaev

  2. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    M. A. Fedotov

Authors
  1. S. N. Shagabutdinova
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  2. M. A. Fedotov
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  3. A. V. Belyaev
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Additional information

Original Russian Text © S.N. Shagabutdinova, M.A. Fedotov, A.V. Belyaev, 2007, published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 2, pp. 146–150.

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Shagabutdinova, S.N., Fedotov, M.A. & Belyaev, A.V. The study of induced aquation of Rh(III) sulfate complexes. Russ J Coord Chem 33, 140–144 (2007). https://doi.org/10.1134/S1070328407020121

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  • DOI: https://doi.org/10.1134/S1070328407020121

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