Abstract
The rate constants, partial orders in the reagent concentrations and activation parameters of interaction of macroheterocyclic compound based on consecutively alternating fragments of thiazole and 3,4-bis(4-tert-butylphenyl)pyrole (3 + 3) with dehydrated Ni(OAc)2 in dry DNF depending on the reagent concentrations and temperature were determined. Within a narrow range of the salt concentrations ((1.58−1.87) × 10−4 mol/l), the third-order equation of the reaction rate was obtained i.e., the first order in a macrocyclic ligand and the second order in a salt, which was interpreted in terms of the mechanism of a stepwise coordination with three [Ni(OAc)]+ ions that is reversible only at the second step. Because of the low solubility of McH3, the monomer-dimer equilibrium also becomes kinetically significant. The constant of McH3 dimerization in DMF at 298 K equal to 1.6 × 105 mol−1 was determined by spectrophotometric titration.
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Sessler, J.L., Gebauer, A., and Weghorn, S.J., Porphyrin Handbook, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., New York: Academic, 2000, vol. 2, p. 55.
Sessler, J.L. and Seidel, D., Ang. Chem., Int. Ed., 2003, vol. 42, p. 5134.
Shimizu, S., Anard, V.G., Taniguchi, R., et al., J. Am. Chem. Soc., 2004, vol. 126, no. 26, p. 12280.
Islyaikin, M.K., Danilova, E.A., Yagodarova, L.D., et al., Org. Lett., 2001, vol. 3, no. 14, p. 2153.
Kobayashi, N., Inagaki, S., Nemykin, V.N., and Nonomura, T., Angew. Chem., Int. Ed., 2001, vol. 40, no. 14, p. 2710.
Rodríguez-Morgade, M.S., Porphyrin Handbook, Kadish, K.M., Smith, K.M., and Guilard, R.N.Y., Eds., New York: Academic, 2003, vol. 15, p. 125.
Islyaikin, M.K., Danilova, E.A., and Yagodarova, L.D., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2003, vol. 46, no. 2, p. 3.
Lomova, T.N., Suslova, E.E., Danilova, E.A., and Islyaikin, M.K., Zh. Fiz. Khim., 2005, vol. 79, no. 2, p. 263 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 79, no. 2, p. 201].
Islyaikin, M.K., Khelevina, O.G., Danilova, E.A., and Lomova, T.N., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2004, vol. 47, no. 5, p. 35.
Vinogradov, S.V., Cand. Sci. (Chem.) Dissertation, Ivanovo: Institute of Solution Chemistry, USSR Acad. Sci., 1989.
Gordon, A.J. and Ford, R.A., A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.
Danilova, E.A. and Islyaikin, M.K., Uspekhi khimii porfirinov (Advances in Porphyrin Chemistry), Golubchikov, O.A., Ed., 2004, vol. 4, p. 356.
Langford, C.H. and Gray, H.B., Ligand Substitution Processes, New York: Benjamin, 1965.
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Original Russian Text © T.N. Lomova, E.G. Mazhzhukhina, E.A. Danilova, M.K. Islyaikin, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 11, pp. 869–873.
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Lomova, T.N., Mozhzhukhina, E.G., Danilova, E.A. et al. Thiadiazoloporphyrinoids. Coordination of hexa(4-tert-butylphenyl)-substituted trithiadiazoltripyrrol macrocycle with Ni(II) in DMF. Russ J Coord Chem 32, 837–840 (2006). https://doi.org/10.1134/S107032840611011X
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DOI: https://doi.org/10.1134/S107032840611011X