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Zn complex with N-(4′-Benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine: Synthesis, crystal structure, and vibration spectrum

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Abstract

The ZnL2 complex (I) (HL = N-(4′-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine) is synthesized and studied by IR spectroscopy and X-ray diffraction analysis. The crystals are monoclinic: a = 23.139(2) Å, b = 19.931(2) Å, c = 14.604(2) Å, β = 121.20(1)°, Z = 4, space group C2/c, R = 0.751 for 766 reflections with I > 2σ(I). The Zn atom in a molecule of the complex lies on a twofold axis and is coordinated at the vertices of a distorted tetrahedron by four N atoms of two HL ligands (average Zn-N distance 2.024 Å).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    L. Kh. Minacheva, I. S. Ivanova, A. V. Dorokhov & V. S. Segienko

  2. Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194/3, Rostov-on-Don, 344104, Russia

    A. S. Burlov & A. D. Garnovskii

  3. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. Yu. Tsivadze

Authors
  1. L. Kh. Minacheva
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  2. I. S. Ivanova
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  3. A. V. Dorokhov
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  4. A. S. Burlov
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  5. A. D. Garnovskii
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  6. V. S. Segienko
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  7. A. Yu. Tsivadze
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Original Russian Text © L. Kh. Minacheva, I.S. Ivanova, A.V. Dorokhov, A.S. Burlov, A.D. Garnovskii, V. S. Segienko, A.Yu. Tsivadze, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 3, pp. 174–180.

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Minacheva, L.K., Ivanova, I.S., Dorokhov, A.V. et al. Zn complex with N-(4′-Benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine: Synthesis, crystal structure, and vibration spectrum. Russ J Coord Chem 32, 166–172 (2006). https://doi.org/10.1134/S107032840603002X

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  • DOI: https://doi.org/10.1134/S107032840603002X

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