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Extraction of Actinides and Lanthanides from Nitric Acid Solutions with Diphosphine Dioxides in the Presence of an Ionic Liquid

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Radiochemistry Aims and scope

Abstract

The effect of the ionic liquid—1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide—on the extraction of lanthanides(III), U(VI) and Th(IV) from nitric acid solutions with 1,2-bis(diphenylphosphinyl)-ethane I and 1,2-bis(diphenylphosphinyl)benzene II was studied. The stoichiometry of the extracted complexes was determined. A solution of dioxide II in dichloroethane extracts metal ions much more efficiently than a solution of dioxide I. It was established that in the presence of an ionic liquid in the organic phase, the efficiency of extraction of metal ions from nitrate solutions with solutions of dioxide I increases significantly, and that of dioxide II decreases. Thus, in the presence of an ionic liquid in the organic phase, dioxide II is significantly inferior to dioxide I in terms of the efficiency of Ln(III), U(VI) and Th(IV) extraction from nitric acid solutions, which is attributed to a significantly greater ability of dioxide II to extract HTf2N.

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Funding

The work was carried out within the framework of the State Assignment (2023) of the Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Institute of Solid State Physics, Russian Academy of Sciences, and Nesmeyanov Institute of Organoelement Compounds. The synthesis of the starting compounds was carried out with financial support from the Russian Science Foundation (project 20-13-00329).

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Authors and Affiliations

  1. Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    A. N. Turanov

  2. Institute of Microelectronics Technology and Highly Pure Materials, Russian Academy of Sciences, Chernogolovka, 142432, Moscow oblast, Russia

    V. K. Karandashev

  3. Nesmeyanov Institute of Organoelement Compounds, 119334, Moscow, Russia

    O. I. Artyushin & V. K. Brel’

Authors
  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. O. I. Artyushin
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  4. V. K. Brel’
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Corresponding author

Correspondence to V. K. Brel’.

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Translated from Radiokhimiya, No. 5, pp. 410–417, October, 2023 https://doi.org/10.31857/S0033831123050027

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Turanov, A.N., Karandashev, V.K., Artyushin, O.I. et al. Extraction of Actinides and Lanthanides from Nitric Acid Solutions with Diphosphine Dioxides in the Presence of an Ionic Liquid. Radiochemistry 65, 530–537 (2023). https://doi.org/10.1134/S1066362223050028

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  • DOI: https://doi.org/10.1134/S1066362223050028

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