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A Precision Spectrophotometric Method for Determining the Mass Fraction of Nuclear Materials

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Radiochemistry Aims and scope

Abstract

High-precision determination of the mass fraction of elements with the relative random deviation Sr < 0.1% is required for the account and control of radionuclides in nuclear materials to ensure nonproliferation of fissile nuclides (U and Pu). Therefore, improvement of methods for determining radionuclides, especially uranium and plutonium, in various nuclear materials was always a topical problem. In addition, the use of precision methods for the determination of these elements is required in certification of reference samples, including determination of the uranium and plutonium mass fractions in nuclear materials produced for nuclear industry. Various analytical methods, including a spectrophotometric method based on commercially available devices such as Shimadzu UV, have been developed for this purpose.

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REFERENCES

  1. ESARDA Bull., 1994, no. 23 (March), pp. 15–27.

  2. Stepanov, A.V., Nikitina, S.A., Karasev, V.T., Belyaev, B.N., Stepanov, D.A., Pevtsova, E.V., and Bogoroditskii, A.B., Radiochemistry, 2002, vol. 44, no. 2, pp. 178–182.

    Article  CAS  Google Scholar 

  3. Stepanov, A.V., Nikitina, S.A., Karasev, V.T., et al., Tr. Radiev. Inst. im. V.G. Khlopina, 2003, vol. X, pp. 50–58.

    Google Scholar 

  4. Stepanov, A.V., Stepanov, D.A., Nikitina, S.A., Gogoleva, T.D., Grigor’eva, M.G., Bulyanitsa, L.S., Panteleev, Yu.A., Pen’kin, M.V., Pevtsova, E.V., and Domkin, V.D., Radiochemistry, 2006, vol. 48, no. 2, pp. 198–203.

    Article  CAS  Google Scholar 

  5. Preparation of NBL CRM-144 solutions, Report no. 2000/2-288, St. Petersburg: Khlopin Radium Inst., 2000.

  6. Determination of the mass fraction and isotope composition of plutonium in a 240Pu monoisotope solution, Report no. 2908-I, St. Petersburg: Khlopin Radium Inst., 2001.

  7. Preparation of a 239Pu/240Pu two-isotope solution for calibration of mass spectrometers, Report no. 2907-I, St. Petersburg: Khlopin Radium Inst., 2001.

  8. Bulyanitsa, L.S., Stepanov, A.V., Belyaev, B.N., et al., Abstracts of Papers, Tret’ya Rossiiskaya konferentsiya po radiokhimii “Radiokhimiya-2000” (Third Russian Conf. on Radiochemistry “Radiochemistry-2000”), St. Petersburg, Nov. 28–Dec. 01, 2000, p. 73.

  9. Panteleev, Yu.A., Nikitina, S.A., Bulyanitsa, L.S., et al., Development of a state reference sample of plutonium-242 solution composition and of a reference sample of plutonium metal, Report no. 3050-I, St. Petersburg: Khlopin Radium Inst., 2004.

    Google Scholar 

  10. Panteleev, Yu.A., Nikitina, S.A., Bulyanitsa, L.S., et al., Preparation and certification analysis of two reference samples of nitric acid 242Pu solutions as spikes for isotope dilution mass spectrometry (IDMS), Report no. F-04/65, St. Petersburg: Kirsi Branch of Khlopin Radium Inst., 2005.

    Google Scholar 

  11. Panteleev, Yu.A., Nikitina, S.A., Bulyanitsa, L.S., et al., Results of measuring the mass fraction of plutonium in the material of the working body of RTSO reference sample of highly calcined low-burn-up plutonium dioxide by internal standardization spectrophotometric method, Report no. 3115-I, St. Petersburg: Khlopin Radium Inst., 2005.

    Google Scholar 

  12. Results of metrological certification of a reference sample of plutonium dioxide composition for the plutonium content, Report of the Bochvar High-Tech Research Inst. of Inorganic Materials, Moscow, 2006.

  13. Nikitina, S.A., Gogoleva, T.D., and Voronina, S.N., Radiochemistry, 2012, vol. 54, no. 5, pp. 419–430.

    Article  CAS  Google Scholar 

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Correspondence to M. A. Shvindin.

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Shvindin, M.A., Myalochkin, D.L. & Sbitneva, V.V. A Precision Spectrophotometric Method for Determining the Mass Fraction of Nuclear Materials. Radiochemistry 65, 249–252 (2023). https://doi.org/10.1134/S1066362223020169

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  • DOI: https://doi.org/10.1134/S1066362223020169

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