Abstract
Published data on the application of ionic liquids (ILs) and binary extractants in the extraction and separation of rare-earth metals (REMs) and radioactive elements, published in Russia and abroad during the last 5–10 years, are reviewed. An analysis of published studies demonstrated that new ILs used as solvents or additives to improve the extraction and separation of actinides and lanthanides are being presently developed. Difunctionalized and also binary extractants are widely used to separate REMs. Various extractive systems with ILs and factors affecting the efficiency of extraction and separation of actinides and lanthanides are considered and attention is given to the composition of compounds of the elements being extracted, selectivity of extractants, possibility of re-extracting metals from the organic phase, and practical use of ILs.
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REFERENCES
Wang, W., Chen, J., Liu, H.Z., et al., Chin. J. Appl. Chem., 2015, vol. 32, pp. 733–742.
Shultz, Z., Gaitor, J.C., Burton, R.D., et al., J. Mol. Liq., 2019, vol. 276, pp. 334–337.
Turanov, A.N., Karandashev, V.K., and Yarkevich, A.N., Radiochemistry, 2013, vol. 55, no. 4, pp. 382–387. https://doi.org/10.1134/S1066362213040073
Turanov, A.N., Karandashev, V.K., and Yarkevich, A.N., Radiochemistry, 2016, vol. 58, no. 4, pp. 389–393. https://doi.org/10.1134/S106636221604007X
Nakashima, K., Kubota, F., Maruyama, T., and Goto, M., Anal. Sci., 2003, vol. 19, pp. 1097–1098.
Sun, T., Zhang, Y., Wu, Q., et al., Solvent Extr. Ion Exch., 2017, vol. 35, pp. 408–422.
Rout, A., Venkatesan, K.A., Srinivasan, T.G., and Rao, P.R.V., Radiochim. Acta, 2009, vol. 97, pp. 719–725.
Rao, C.V., Rout, A., and Venkatesan, K.A., Sep.Purif. Technol., 2019, vol. 213, pp. 545–552.
Turanov, A.N., Karandashev, V.K., and Yarkevich, A.N., Radiochemistry, 2018, vol. 60, no. 2, pp. 170–176. https://doi.org/10.1134/S1066362218020078
Rout, A., Venkatesan, K.A., Srinivasan, T.G., and Rao, P.R.V., J. Hazard. Mater., 2012, vol. 221–222, pp. 62–67.
Shen, Y., Tan, X., Wang, L., and Wu, W., Sep. Purif. Technol., 2011, vol. 78, pp. 298–302.
Rama, R., Rout, A., Venkatesana, K.A., and Antony, M.P., Sep. Purif. Technol., 2018, vol. 196, pp. 166–173.
Rout, A., Chatterjee, K., Venkatesan, K.A., et al., Sep. Purif. Technol., 2016, vol. 159, pp. 43–49.
Rout, A., Venkatesan, K.A., Srinivasan, T.G., and Rao, P.R.V., Desalin. Water Treat., 2012, vol. 38, pp. 179–183.
Zarrougui, R. and Mdimagh, R., J. Hazard. Mater., 2018, vol. 342, pp. 464–476.
Li, H.Y., Wang, B., Zhang, L., and Shen, L.H., J. Radioanal. Nucl. Chem., 2015, vol. 303, pp. 433–440.
Hoogerstraete, T.V., Wellens, S., Verachtert, K., and Binnemans, K., Green Chem., 2013, vol. 15, pp. 919–927.
Parmentier, D., Metz, S.J., and Kroon, M.C., Green Chem., 2013, vol. 15, pp. 205–209.
Wellens, S., Goovaerts, R., Moller, C., et al., Green Chem., 2013, vol. 15, pp. 3160–3164.
Rout, A., Kumerasan, R., Venkatesan, K.A., and Antony, M.P., J. Radioanal. Nucl. Chem., 2017, vol. 313, pp. 505–513.
Turanov, A.N., Karandashev, V.K., Boltoeva, M., et al., Sep. Purif. Technol., 2016, vol. 164, pp. 97–106.
Panja, S., Mohapatra, P.K., Tripathi, S.C., et al., Sep. Purif. Technol., 2012, vol. 96, pp. 289–295.
Yoon, S.J., Lee, J.G., Tajima, H., et al., J. Ind. Eng. Chem., 2010, vol. 16, pp. 350–354.
Zhu, M.H., Zhao, J.M., Li, Y.B., et al., Green Chem., 2015, vol. 17, pp. 2981–2993.
Kubota, F., Shimobori, Y., Baba, Y., et al., J. Chem. Eng. Jpn., 2011, vol. 44, pp. 307–312.
Rout, A., Souza, E.R., and Binnemans, K., RSC Adv., 2014, vol. 4, no. 23, pp. 11899–11906.
Yang, F., Kubota, F., Kamiya, N., Goto, M., Solvent Extr. Res. Dev., Jpn., 2013, vol. 20, pp. 225–232.
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Russ. J. Inorg. Chem., 2008, vol. 53, no. 6, pp. 970–975. https://doi.org/10.1134/S0036023608060272
Turanov, A.N., Karandashev, V.K., Baulin, V.E., et al., Russ. J. Inorg. Chem., 2016, vol. 61, no. 3, pp. 377–383 https://doi.org/10.1134/S0036023616030232
Turanov, A.N., Karandashev, V.K., Baulin, V.E., et al., Russ. J. Inorg. Chem., 2016, vol. 61, no. 11, pp. 1479–1482 https://doi.org/10.1134/S0036023616110218
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Radiochemistry, 2008, vol. 50, no. 3, pp. 229–235.
Shimojo, K., Kurahashi, K., and Naganava, H., Dalton Trans., 2008, vol. 37, pp. 5083–5088.
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Solvent Extr. Ion Exch., 2008, vol. 26, pp. 77–99.
Turanov, A.N., Karandashev, V.K., and Baulin, V.E., Russ. J. Inorg. Chem., 2012, vol. 57, no. 2, pp. 292–296. https://doi.org/10.1134/S0036023612020246
Turanov, A.N., Karandashev, V.K., and Yarkevich, A.N., Radiochemistry, 2014, vol. 56, no. 5, pp. 515–519. https://doi.org/10.1134/S1066362214050105
Sun, X., Ji, Y., Guo, L., et al., Sep. Purif. Technol., 2011, vol. 81, pp. 25–30.
Ma, G.L., Yuan, W.J., Dong, Z., et al., Nucl. Sci. Technol., 2015, vol. 26, p. S10305.
Kubota, F., Shimobori, Y., Baba, Y., et al., J. Chem. Eng. Jpn., 2011, vol. 44, pp. 307–312.
Yang, F., Baba, Y., Kubota, F., et al., Solvent Extr. Res. Dev., Jpn., 2012, vol. 19, pp. 69–76.
Yang, F., Kubota, F., Baba ,Y., et al., J. Hazard. Mater., 2013, vol. 254–255, pp. 79–88.
Rout, A. and Binnemans, K., Dalton Trans., 2015, vol. 44, pp. 1379–1387.
Atanassova, M. and Billard, I., J. Solution Chem., 2015, vol. 44, pp. 606–620.
Sun, X., Peng, B., Chen, J., et al., Talanta, 2008, vol. 74, pp. 1071–1074.
Sahin, A.K., Vossenkaul, D., Stoltz, N., et al., Hydrometallurgy, 2017, vol. 169, pp. 59–67.
Mei, X., Yue, Z., Ma, Q., et al., J. Mol. Liq., 2018, vol. 272, pp. 1001–1018.
Ramos, T.J.S., Berton, G.H., Cassol, T.M., and Junior, S.A., J. Mater. Chem. P, 2018, vol. 6, pp. 6270–6279.
Zhang, Z., Salih, A.M., Li, M., and Yang, B., Energy Fuels, 2014, vol. 28, no. 4, pp. 2802–2810.
Djellal, A. and Amirat, S., Orient. J. Chem., 2015, vol. 31, no. 4, pp. 2391–2394.
Billard, I., Ouadi, A., and Gaillard, C., Dalton Trans., 2013, vol. 42, pp. 6203–6212.
Bell, T.J. and Ikeda, Y., Dalton Trans., 2011, vol. 40, pp. 10125–10130.
Kuz’min, V.I. and Khol’kin, A.I., Izv. Sib. Otd. Akad.Nauk SSSR, Ser. Khim. Nauk, 1989, no. 7, pp. 3–7.
Rout, A., Kotlarska, J., Dehaen, W., and Binnemans, K., Phys. Chem. Chem. Phys., 2013, vol. 15, pp. 16533–16541.
Rout, A., Karmakar, S., Venkatesan, K.A., et al., Sep. Purif. Technol., 2011, vol. 81, pp. 109–115.
Rout, A., Venkatesan, K.A., Srinivasan, T.G., and Rao, P.R.V., Sep. Purif. Technol., 2012, vol. 97, pp. 164–171.
Kalyakin, S.N., Kuzmin, V.I., and Mulagaleeva, M.A., J. Mol. Liq., 2019, vol. 273, pp. 45–49.
Panigrahi, M., Grabda, M., Kozak, D., et al., Sep. Purif. Technol., 2016, vol. 171, pp. 263–269.
Xiong, Y., Kuang, W., Zhao, J., and Liu, H., Sep. Purif. Technol., 2017, vol. 179, pp. 349–356.
Zuo, Y., Liu, Y., Chen, J., and Li, D.Q., Ind. Eng. Chem. Res., 2008, vol. 47, pp. 2349–2355.
Gras, M., Papaiconomou, N., Chainet, E., et al., Sep. Purif. Technol., 2017, vol. 178, pp. 169–177.
Larsson, K. and Binnemans, K., Hydrometallurgy, 2015, vol. 156, pp. 206–214.
Hoogerstraete, T.V. and Binnemans, K., Green Chem., 2014, vol. 16, pp. 1594–1606.
Rout, A., Venkatesan, K.A., Srinivasan, T.G., and Rao, P.R.V, Sep. Sci. Technol., 2013, vol. 48, pp. 2576–2581.
Zhao, Z., Lyu, H., Guo, X., et al., Hydrometallurgy, 2017, vol. 174, pp. 234–247.
Kumari, A., Sinha, M.K., Sahu, S.K., and Pandey, B.D., Solvent Extr. Ion Exch., 2016, vol. 34, pp. 469–484.
Dong, Y., Sun, X., Wang, Y., and Chai, Y., Hydrometallurgy, 2015, vol. 157, pp. 256–260.
Sobekova-Foltova, S., Hoogerstraete, T.V., Banerjee, D., and Binnemans, K., Sep. Purif. Technol., 2019, vol. 210, pp. 209–218.
Sun, X., Ji, Y., Hu, F., et al., Talanta., 2010, vol. 81, pp. 1877–1883.
Guo, L., Chen, J., Shen, L., et al., ACS Sustain. Chem. Eng., 2014, vol. 2, no. 8, pp. 1968–1975.
Quinna, J.E., Soldenhoff, K.H., and Stevens, G.W., Hydrometallurgy, 2017, vol. 169, pp. 621–628.
Shen, L., Chena, J., Chena, L., et al., Hydrometallurgy, 2016, vol. 161, pp. 152–159.
Pavon, S., Fortuny, A., Coll, M.T., and Sastre, A.M., J. Environ. Manag., 2018, vol. 222, pp. 359–367.
Pavon, S., Fortuny, A., Coll, M.T., and Sastre, A.M., Waste Manag., 2018, vol. 82, pp. 241–248.
Padhan, E. and Sarangi, K., Hydrometallurgy, 2017, vol. 167, pp. 134–140.
Dutta, B., Ruhela, R., Yadav, M., et al., Sep. Purif. Technol., 2017, vol. 175, pp. 158–163.
Parmentier, D., Hoogerstraete, T.V., Metz, S.J., et al., Ind. Eng. Chem. Res., 2015, vol. 54, pp. 5149–5158.
Chena, L., Chena, J., Lia, H., et al., Sep. Purif. Technol., 2018, vol. 207, pp. 179–186.
Ma, L., Zhao, Z., Dong, Y., and Sun, X., Sep. Purif. Technol., 2017, vol. 174, pp. 474–481.
Dong, Y., Sun, Kh., Wang, Y., et al., ACS Sustainable Chem. Eng., 2016, vol. 4, no. 3, pp. 1573–1580.
Yang, H.L., Wang, W., Cui, H.M., and Chen, J., Chin J. Anal. Chem., 2011, vol. 39, no. 10, pp. 1561–1566.
Yang, H., Chen, J., Wang, W., et al., Sci. China Chem., 2016, vol. 59, no. 5, pp. 532–537.
Chen, J., Huang, C., Wang, Y., et al., J. Rare Earth., 2016, vol. 34, no. 12, pp. 1252–1259.
Suna, X., Luo, H., and Dai, S., Talanta, 2012, vol. 90, pp. 132–137.
Rout, A. and Binnemans, K., Ind. Eng. Chem. Res., 2014, vol. 53, pp. 6500–6508.
Rout, A., Venkatesan, K.A., Srinivasan, T.G., and Vasudeva Rao, P.R., Sep. Purif. Technol., 2012, vol. 95, pp. 26–31.
Belova, V.V., Martynova, M.M., Baulin, V.E., and Baulin, D.V., Russ. J. Inorg. Chem., 2019, vol. 64, no. 8, pp. 1059–1062. https://doi.org/10.1134/S0036023619080023
Kalyakin, S.N., Kuzmin, V.I., and Mulagaleeva, M.A., Hydrometallurgy, 2015, vol. 151, pp. 116–121.
Kalyakin, S.N., Kuz’min, V.I., and Mulagaleeva, M.A., Khim. Tekhnol., 2015, vol. 16, no. 12, pp. 746–753.
Kalyakin, S.N., Kuz’min, V.I., and Mulagaleeva, M.A., Tsvetn. Met., 2011, no. 3, pp. 51–54.
Egorova, N.S., Belova, V.V., Voshkin, A.A., et al., Zh. Neorg. Khim., 2005, vol. 50, no. 11, pp. 1902–1905.
Belova, V.V., Voshkin, A.A., Kholkin, A.I., Payrtman, A.K., Hydrometallurgy, 2009, vol. 97, pp. 198–203.
Belova, V.V., Voshkin, A.A., Egorova, N.S., and Kholkin, A.I., J. Mol. Liq., 2012, vol. 172, pp. 144–146.
Belova, V.V., Voshkin, A.A., Egorova, N.S., and Khol’kin, A.I., Russ. J. Inorg. Chem., 2010, vol. 55, no. 4, pp. 679–683. https://doi.org/10.1134/S0036023610040224
Belova, V.V., Egorova, N.S., Voshkin, A.A., and Khol’kin, A.I., Khim. Tekhnologiya, 2014, vol. 15, no. 2, pp. 106–111.
Egorova, N.S., Belova, V.V., Voshkin, A.A., et al., Khim. Tekhnol., 2007, vol. 8, no. 10, pp. 460–454.
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The study was carried out under the State assignment to the Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of basic research.
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Translated from Radiokhimiya, 2021, Vol. 63, No. 1, pp. 3–12 https://doi.org/10.31857/S0033831121010019.
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Belova, V.V. Tendencies in Application of Ionic Liquids and Binary Extractants in Extraction and Separation of Lanthanides and Actinides. Radiochemistry 63, 1–10 (2021). https://doi.org/10.1134/S106636222101001X
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DOI: https://doi.org/10.1134/S106636222101001X