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Synthesis and Structure of U(VI), Np(VI), and Pu(VI) 2-Fluorobenzoates

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Abstract

The compounds NH4[AnO2(C6H4FCOO3], where An = U (I), Np (II), or Pu (III), CgH4COO− is the 2-fluorobenzoate anion, were synthesized and studied by single crystal X-ray diffraction. Compounds I–III are isostructural and crystallize in the cubic system, space group P213, Z = 4. The main structural units of I–III are mononuclear complexes [AnO2(C6H4COO)3]− belonging to crystal-chemical group AB31 (A = AnO22+, B01 = C6H4FCOO−). The actinide contraction in the structures of I–III is manifested in a regular decrease in the lengths of the An=0 bonds in the AnO22+ cations and in the volumes of the Voronoi-Dirichlet polyhedra (VDPs) of the An atoms in the series U-Np-Pu. The intermolecular interactions in crystal structures of I–III were analyzed by the method of molecular VDPs.

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Acknowledgments

X-ray diffraction experiments were performed at the Center for Shared Use of Physical Methods of Investigation at the Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences.

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Authors and Affiliations

  1. Samara National Research University, ul. Akademika Pavlova 1, Samara, 443011, Russia

    V. N. Serezhkin & L. B. Serezhkina

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, Moscow, 119071, Russia

    M. S. Grigor’ev, A. M. Fedoseev & N. A. Budantseva

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  1. V. N. Serezhkin
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  2. M. S. Grigor’ev
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  3. A. M. Fedoseev
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  4. N. A. Budantseva
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  5. L. B. Serezhkina
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Correspondence to V. N. Serezhkin.

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Russian Text © The Author(s), 2019, published in Radiokhimiya, 2019, Vol. 61, No. 3, pp. 217–222.

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Serezhkin, V.N., Grigor’ev, M.S., Fedoseev, A.M. et al. Synthesis and Structure of U(VI), Np(VI), and Pu(VI) 2-Fluorobenzoates. Radiochemistry 61, 293–299 (2019). https://doi.org/10.1134/S1066362219030020

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  • DOI: https://doi.org/10.1134/S1066362219030020

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