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Decontamination of irradiated Be from radioactive impurities by precipitation of hydroxides

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Abstract

Decontamination of TV-56 grade Be irradiated in an SM reactor to a neutron fluence of 6 × 1022 cm−2 (E > 0.1 MeV) from radioactive impurities by precipitation of its hydroxide with ammonia in the presence of a complexone, diethylenetriaminepentaacetic acid (DTPA), was studied. The decontamination procedure involved dissolution in hydrochloric acid, addition of the complexone, precipitation of beryllium hydroxide with ammonia, separation of the hydroxide from solution, and washing of the hydroxide precipitate. The radioactivity of the solutions obtained after each decontamination step was determined.

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References

  1. TU (Technical Specification) 95.469-77: Technical-Grade Sintered Beryllium, 1998.

  2. Levakov, B.I., Anokhin, Yu.P., Gavrilov, V.D., et al., Radiokhimiya, 2011, vol. 53, no. 6, pp. 538–541.

    Google Scholar 

  3. Tranter, T.J., Tillotson, R.D., Mann, N.R., and Longhurst, G.R., in Proc. 7th IEA Int. Workshop on Beryllium Technology, Idaho National Laboratory, 2006, pp. 107–110.

  4. Rabaglino, E., Helium and Tritium in Neutron-Irradiated Beryllium, Report FZKA 6939, Forschungszentrum Karlsruhe, 2004.

  5. Novoselova, A.V. and Batsanova, L.R., Analilticheskaya khimiya berilliya (Analytical Chemistry of Beryllium), Moscow: Nauka, 1966.

    Google Scholar 

  6. Dyatlova, N.M., Temkina, V.Ya., and Popov, K.I., Kompleksony i kompleksonaty metallov (Complexones and Metal Complexonates), Moscow: Khimiya, 1988.

    Google Scholar 

  7. Brewer, P., Analyst, 1952, vol. 77, p. 539.

    CAS  Google Scholar 

  8. Kawamura, H., Tatenuma, K., Hasegawa, Y., and Sakamoto, N., in Proc. 2nd IEA Int. Workshop on Beryllium Technology, Idaho National Laboratory, 1995, pp. 261–268.

  9. Kotov, V., Savchuk, V., Zorin, B., et al., Research and Development of Recycling Technology of Irradiated Beryllium, 9 th Int. Workshop on Be for Fusion, Almaty, September 15–17, 2009.

  10. Savchuk, V., Arinov, B., and Martsifei, I., Researches of Beryllium Recycling, 9th Int. Workshop on Be for Fusion, Almaty, September 15–17, 2009.

  11. Chakin, V.P., Levakov, B.I., and Svyatkin, M.N., RF Patent 2 363 060, Appl. October 8, 2007, Publ. July 27, 2009.

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Correspondence to A. O. Posevin.

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Original Russian Text © B.I. Levakov, A.O. Posevin, A.S. Pokrovskii, M.N. Svyatkin, A.B. Kharlov, N.F. Demchenko, 2012, published in Radiokhimiya, 2012, Vol. 54, No. 4, pp. 328–332.

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Levakov, B.I., Posevin, A.O., Pokrovskii, A.S. et al. Decontamination of irradiated Be from radioactive impurities by precipitation of hydroxides. Radiochemistry 54, 358–362 (2012). https://doi.org/10.1134/S106636221204008X

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  • DOI: https://doi.org/10.1134/S106636221204008X

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