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Synthesis, crystal structure, and absorption spectra of 2,2′-bipyridine complexes of benzoates of hexavalent U, Np, and Pu

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Abstract

Complex benzoates [{UO2(C10N2H8)C6H5COO}2O2], [NpO2(C10N2H8)(C6H5COO)2], and [PuO2(C10N2H8)(C6H5COO)2] (C10N2H8 is 2,2′-bipyridine) were synthesized in the form of single crystals, and their structure was determined by X-ray diffraction analysis. The absorption spectra of the crystalline U(VI), Np(VI), and Pu(VI) complexes were measured and analyzed.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, block 4, Moscow, 119071, Russia

    M. N. Sokolova, A. A. Bessonov & A. M. Fedoseev

Authors
  1. M. N. Sokolova
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  2. A. A. Bessonov
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  3. A. M. Fedoseev
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Correspondence to A. M. Fedoseev.

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Original Russian Text © M.N. Sokolova, A.A. Bessonov, A.M. Fedoseev, 2012, published in Radiokhimiya, 2012, Vol. 54, No. 4, pp. 313–317.

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Sokolova, M.N., Bessonov, A.A. & Fedoseev, A.M. Synthesis, crystal structure, and absorption spectra of 2,2′-bipyridine complexes of benzoates of hexavalent U, Np, and Pu. Radiochemistry 54, 341–345 (2012). https://doi.org/10.1134/S1066362212040054

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  • DOI: https://doi.org/10.1134/S1066362212040054

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