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A study of the ion-exchange behavior of Pb and Bi as homologs of elements 114 and 115, respectively, in aqueous and aqueous-methanol solutions of HNO3

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Abstract

The ion-exchange behavior of Pb and Bi as homologs of elements 114 and 115, respectively, in aqueous and aqueous-methanol solutions of HNO3 was studied. The distribution coefficients of Bi, Pb, Ra, and some actinides between the ion exchangers and HNO3 solutions were determined in relation to the acid and methanol concentrations in the solution and to the kind of the ion exchanger. The distribution coefficients of Bi and other elements under consideration in sorption on the cation and anion exchangers from mixed aqueousmethanol HNO3 solutions differ considerably. The optimum conditions were found for the isolation of carrier-free short-lived Pb and Bi isotopes and for their separation from actinides and other elements using the ion exchangers and aqueous-methanol HNO3 solutions. The possibility of repeated isolation of short-lived Bi isotopes with their simultaneous separation from the long-lived parent radionuclides (Ac, Ra, Pb) on the cation exchanger (radioisotope generators) using mixed HNO3/CH3OH solution and of on-line preconcentration of these isotopes on the anion exchanger was demonstrated.

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References

  1. Oganessian, Yu.Ts. and Dmitriev, S.N., Usp. Khim., 2009, vol. 78, no. 12, pp. 1165–1176.

    Google Scholar 

  2. Kratz, J.V., The Chemistry of Heavy Elements, Shadel, M., Ed., Dordrecht: Kluwer, 2003, pp. 159–201.

    Google Scholar 

  3. Guseva, L.I., Usp. Khim., 2005, vol. 74, no. 5, pp. 484–502.

    Google Scholar 

  4. Guseva, L.I. and Tikhomirova, G.S., Radiokhimiya, 2002, vol. 44, no. 2, pp. 154–157.

    Google Scholar 

  5. Guseva, L.I., Tikhomirova, G.S., and Dogadkin, N.N., J. Radioanal. Nucl. Chem., 2004, vol. 206, no. 1, pp. 167–172.

    Article  Google Scholar 

  6. Guseva, L.I., Radiokhimiya, 2007, vol. 49, no. 2, pp. 84–88.

    Google Scholar 

  7. Guseva, L.I., Radiokhimiya, 2010, vol. 52, no. 3, pp. 229–233.

    Google Scholar 

  8. Guseva, L.I. and Dogadkin, N.N., Radiokhimiya, 2009, vol. 51, no. 3, pp. 148–152.

    Google Scholar 

  9. Korkisch, J., Feik, F., and Ahluwalla, S.S., Talanta, 1967, vol. 14, no. 9, pp. 1069–1081.

    Article  CAS  Google Scholar 

  10. Guseva, L.I. and Tikhomirova, G.S., Radiokhimiya, 1984, vol. 26, no. 5, pp. 764–770.

    CAS  Google Scholar 

  11. Faris, J.P. and Buchanan, R.F., Anal. Chem., 1964, vol. 36, pp. 1157–1158.

    Article  CAS  Google Scholar 

  12. Nelson, F. and Kraus, K.A., J. Am. Chem. Soc., 1954, vol. 76, no. 23, pp. 5916–5920.

    Article  CAS  Google Scholar 

  13. Guseva, L.I., Lebedev, I.A., Myasoedov, B.F., and Tikhomirova, G.S., Radiokhimiya, 1975, vol. 17, no. 2, pp. 321–327.

    CAS  Google Scholar 

  14. Walter, C.W. and Korkisch, J., Microchim. Acta, 1971, vol. 59, no. 1, pp. 81–95.

    Article  Google Scholar 

  15. Guseva, L.I., Myasoedov, B.F., Tikhomirova, G.S., et al., J. Radioanal. Chem., 1973, vol. 13, pp. 293–300.

    Article  CAS  Google Scholar 

Download references

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  1. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 119991, Russia

    L. I. Guseva

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  1. L. I. Guseva
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Correspondence to L. I. Guseva.

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Original Russian Text © L.I. Guseva, 2012, published in Radiokhimiya, 2012, Vol. 54, No. 1, pp. 57–61.

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Guseva, L.I. A study of the ion-exchange behavior of Pb and Bi as homologs of elements 114 and 115, respectively, in aqueous and aqueous-methanol solutions of HNO3 . Radiochemistry 54, 59–63 (2012). https://doi.org/10.1134/S1066362212010080

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  • DOI: https://doi.org/10.1134/S1066362212010080

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