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Synthesis and properties of complexes of hexavalent actinides with dimethyl sulfoxide [AnO2(DMSO)5](ClO4)2 (An = U, Np, Pu)

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Abstract

The complexes [NpO2(DMSO)5](ClO4)2 (1) and [PuO2(DMSO)5](ClO4)2 (2), isostructural to the known uranyl complex, were synthesized in the form of single crystals. Their crystallographic characteristics were determined by single crystal X-ray diffraction. The IR and electronic absorption spectra of the crystalline U(VI), Np(VI), and Pu(VI) complexes were measured and analyzed.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, block 4, Moscow, 119991, Russia

    N. A. Budantseva, M. S. Grigor’ev, V. I. Mishkevich & A. M. Fedoseev

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  1. N. A. Budantseva
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  2. M. S. Grigor’ev
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  3. V. I. Mishkevich
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  4. A. M. Fedoseev
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Correspondence to N. A. Budantseva.

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Original Russian Text © N.A. Budantseva, M.S. Grigor’ev, V.I. Mishkevich, A.M. Fedoseev, 2011, published in Radiokhimiya, 2011, Vol. 53, No. 6, pp. 486–490.

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Budantseva, N.A., Grigor’ev, M.S., Mishkevich, V.I. et al. Synthesis and properties of complexes of hexavalent actinides with dimethyl sulfoxide [AnO2(DMSO)5](ClO4)2 (An = U, Np, Pu). Radiochemistry 53, 576–581 (2011). https://doi.org/10.1134/S1066362211060026

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  • DOI: https://doi.org/10.1134/S1066362211060026

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