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Extraction and sorption preconcentration of U(VI) and Th(IV) from nitric acid solutions using bis(diphenylphosphorylmethylcarbonylamino)alkanes

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Abstract

Extraction of microamounts of U(VI) and Th(IV) from HNO3 solutions in the form of complexes with polyfunctional neutral organophosphorus compounds, bis(diphenylphosphorylmethylcarbonylamino)alkanes [Ph2P(O)CH2C(O)NH]2(CH2) n (n = 3, 5, 8), was studied. The influence of the extractant structure on the efficiency and selectivity of the extraction of U(VI) and Th(IV) was examined, and the stoichiometry of the extractable complexes was determined. The examined compounds exhibit higher extraction ability and selectivity to metal ions in HNO3 solutions, compared to the alkylamide Ph2P(O)CH2C(O)NHC9H19. The possibility of selective recovery and preconcentration of U(VI) and Th(IV) from nitric acid solutions with a complexing sorbent prepared by noncovalent immobilization of bis(diphenylphosphorylmethylcarbonylamino)pentane on a macroporous polymeric matrix was demonstrated.

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References

  1. Cortina, J.L. and Warshawsky, A., Ion Exch. Solvent Extr., 1997, vol. 13, pp. 195–293.

    CAS  Google Scholar 

  2. Horwitz, E.P., McAlister, D.R., and Dietz, M.L., Sep. Sci. Technol., 2006, vol. 41, pp. 2163–2182.

    Article  CAS  Google Scholar 

  3. Chmutova, M.K., Litvina, M.N., Pribylova, G.A., et al., Radiokhimiya, 1999, vol. 41, no. 4, pp. 331–335.

    Google Scholar 

  4. Horwitz, E.P., Dietz, M.L., Nelson, D.M., et al., Anal. Chim. Acta, 1990, vol. 238, pp. 263–271.

    Article  CAS  Google Scholar 

  5. Turanov, A.N., Karandashev, V.K., Yarkevich, A.N., et al., Radiokhimiya, 2002, vol. 44, no. 6, pp. 506–511.

    Google Scholar 

  6. Morgalyuk, V.P., Molochnikova, N.P., Myasoedova, G.V., et al., Radiokhimiya, 2005, vol. 47, no. 2, pp. 167–170.

    Google Scholar 

  7. Artyushina, O.I., Sharova, E.V., Odinets, I.L., et al., Izv. Ross. Akad. Nauk, Ser. Khim., 2004, no. 11, pp. 2394–2402.

  8. Medved’, T.Ya., Chmutova, M.K., Nesterova, N.P., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1981, no. 9, pp. 2121–2127.

  9. Horwitz, E.P., Kalina, D.G., Kaplan, L., et al., Sep. Sci. Technol., 1982, vol. 17, no. 10, pp. 1261–1279.

    Article  CAS  Google Scholar 

  10. Myasoedov, B.F., Chmutova, M.K., Kochetkova, N.E., et al., Solvent Extr. Ion Exch., 1986, vol. 4, no. 1, pp. 61–81.

    Article  CAS  Google Scholar 

  11. Rozen, A.M., Nikolotova, Z.I., and Kartasheva, N.A., Radiokhimiya, 1986, vol. 28, no. 3, pp. 407–423.

    CAS  Google Scholar 

  12. Horwitz, E.P., Martin, K.A., Diamond, H., and Kaplan, L., Solvent Extr. Ion Exch., 1986, vol. 4, no. 3, pp. 449–494.

    Article  CAS  Google Scholar 

  13. Chmutova, M.K., Ivanova, L.A., Kochetkova, N.E., et al., Radiokhimiya, 1995, vol. 37, no. 5, pp. 422–426.

    CAS  Google Scholar 

  14. Chmutova, M.K., Litvina, M.N., Pribylova, G.A., et al., Radiokhimiya, 1995, vol. 37, no. 5, pp. 430–435.

    CAS  Google Scholar 

  15. Litvina, M.N., Chmutova, M.K., Myasoedov, B.F., and Kabachnik, M.I., Radiokhimiya, 1996, vol. 38, no. 6, pp. 525–530.

    Google Scholar 

  16. Litvina, M.N., Chmutova, M.K., Pribylova, G.A., et al., Radiokhimiya, 1998, vol. 40, no. 6, pp. 550–554.

    Google Scholar 

  17. Turanov, A.N., Karandashev, V.K., Yarkevich, A.N., et al., Radiokhimiya, 2004, vol. 46, no. 5, pp. 427–432.

    Google Scholar 

  18. Kochetkova, N.E., Koiro, O.E., Nesterova, N.P., et al., Radiokhimiya, 1986, vol. 28, no. 3, pp. 338–345.

    CAS  Google Scholar 

  19. Turanov, A.N., Karandashev, V.K., and Bondarenko, N.A., Radiokhimiya, 2006, vol. 48, no. 2, pp. 158–163.

    Google Scholar 

  20. Arnaud-Neu, F., Bohmer, V., Dozol, J.-F., et al., J. Chem. Soc., Perkin Trans. 2, 1996, pp. 1175–1182.

  21. Lambert, T.N., Jarvinen, G.D., and Gopalan, A.S., Tetrahedron Lett., 1999, vol. 40, pp. 1613–1616.

    Article  CAS  Google Scholar 

  22. Delmau, L.H., Simon, N., Schwing-Weill, M.-J., et al., Sep. Sci. Technol., 1999, vol. 34, pp. 863–876.

    CAS  Google Scholar 

  23. Turanov, A.N., Karandashev, V.K., Baulin, V.E., and Tsvetkov, E.N., Zh. Neorg. Khim., 1995, vol. 40, no. 11, pp. 1926–1930.

    CAS  Google Scholar 

  24. Rozen, A.M. and Krupnov, B.V., Usp. Khim., 1996, vol. 65, no. 11, pp. 1052–1079.

    CAS  Google Scholar 

  25. Turanov, A.N., Karandashev, V.K., Kharitonov, A.V., et al., Radiokhimiya, 2000, vol. 42, no. 4, pp. 349–353.

    Google Scholar 

  26. Morgalyuk, V.P., Molochnikova, N.P., Myasoedova, G.V., and Tananaev, I.G., Radiokhimiya, 2006, vol. 48, no. 4, pp. 339–343.

    Google Scholar 

  27. Karandashev, V.K., Turanov, A.N., Kuss, H.-M., et al., Microchim. Acta, 1998, vol. 130, pp. 47–54.

    Article  CAS  Google Scholar 

  28. Yatsimirskii, K.B., Kostromina, N.A., Sheka, Z.A., et al., Khimiya kompleksnykh soedinenii redkozemel’nykh metallov (Chemistry of Coordination Compounds of Rare-Earth Metals), Kiev: Naukova Dumka, 1966.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Solid State Physics, Russian Academy of Sciences, Institutskaya ul. 2, Chernogolovka, Moscow oblast, 142432, Russia

    A. N. Turanov

  2. Institute of Technological Problems of Microelectronics and Ultrapure Materials, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    V. K. Karandashev

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    E. V. Sharova, O. I. Artyushin & I. L. Odinets

Authors
  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. E. V. Sharova
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  4. O. I. Artyushin
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  5. I. L. Odinets
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Correspondence to A. N. Turanov.

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Original Russian Text © A.N. Turanov, V.K. Karandashev, E.V. Sharova, O.I. Artyushin, I.L. Odinets, 2010, published in Radiokhimiya, 2010, Vol. 52, No. 3, pp. 219–223.

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Turanov, A.N., Karandashev, V.K., Sharova, E.V. et al. Extraction and sorption preconcentration of U(VI) and Th(IV) from nitric acid solutions using bis(diphenylphosphorylmethylcarbonylamino)alkanes. Radiochemistry 52, 258–263 (2010). https://doi.org/10.1134/S1066362210030069

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  • DOI: https://doi.org/10.1134/S1066362210030069

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