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Conversion of I2 into ionic species on composite materials in the NPP primary coolant

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Abstract

The conversion of I2 into its ionic species in aqueous solutions, including the simulated primary coolant, at 20, 40, and 60°C on the solid phase of composite materials prepared by modification of KU-2 cation exchanger containing d elements was studied. These materials are capable of converting I2 into its ionic species to 99% both in distilled water and in a solution corresponding in its composition to the aqueous primary coolant of NPP with WWER-type reactors. Practically complete conversion of I2 (to more than 95.0%) is attained in 15 min. AV-18 anion exchanger is capable of sorbing I2 in the form of I 3 from aqueous solution with the distribution coefficients K d >103 ml g−1 upon 24-h contact of the solid and liquid phases at V/m = 100.

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References

  1. Kulyukhin, S.A., Mizina, L.V., Rumer, I.A., and Krasavina, E.P., Radiokhimiya, 2008, vol. 50, no. 3, pp. 258–260.

    Google Scholar 

  2. Krasavina, E.P., Kulyukhin, S.A., Mizina, L.V., et al., Abstracts of Papers, VIII Vserossiiskaya konferentsiya “Fizikokhimiya ul’tradispersnykh (nano-)system” (VIII All-Russia Conf. “Physical Chemistry of Ultradisperse and Nanosystems”), Belgorod, 2008, pp. 279–280.

  3. Kulyukhin, S.A., Mizina, L.V., Konovalova, N.A., et al., Abstracts of Papers, Mezhdunarodnyi forum po nanotekhnologiyam (Int. Forum on Nanotechnologies), Moscow, 2008, vol. 1, pp. 342–344.

    Google Scholar 

  4. Kulyukhin, S.A., Mizina, L.V., Tishina, A.A., and Krasavina, E.P., RF Patent Application no. 2 009 121 629, Applied June 8, 2009.

  5. Charlot, G., Les methods de la chimie analytique. Analyse quantitative minerale, Paris: Masson, 1961, 4th ed. Translated under the title Metody analiticheskoi khimii. Kolichestvennyi analiz neorganicheskikh soedinenii, Moscow: Khimiya, 1957, vol. 2, p. 1108.

    Google Scholar 

  6. Ksenzenko, V.I. and Stashkevich, D.S., Khimiya i tekhnologiya broma, ioda i ikh soedinenii (Chemistry and Technology of Bromine, Iodine, and Their Compounds), Moscow: Khimiya, 1979.

    Google Scholar 

  7. Glanneskog, H., Liljenzin, J.-O., and Sihver, L., J. Nucl. Mater., 2006, vol. 348, pp. 87–93.

    Article  Google Scholar 

  8. Fedushchak, T.A., Ermakov, A.E., Uimin, M.A., et al., Zh. Fiz. Khim., 2008, vol. 82, no. 4, pp. 708–712.

    Google Scholar 

  9. Lidin, R.A., Andreeva, L.L., and Molochko, V.A., Konstanty neorganicheskikh veshchestv: Spravochnik (Constants of Inorganic Substances: Handbook), Moscow: Drofa, 2006, pp. 552–578.

    Google Scholar 

  10. Spravochnik khimika (Chemist’s Handbook), Moscow: Khimiya, 1964, vol. 3, p. 127.

  11. Kulyukhin, S.A., Mizina, L.V., Rumer, I.A., et al., RF Patent no. 2 345 431, Priority of January 17, 2007, Registered January 27, 2009.

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Correspondence to S. A. Kulyukhin.

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Original Russian Text © S.A. Kulyukhin, L.V. Mizina, A.A. Tishina, I.A. Rumer, E.P. Krasavina, 2010, published in Radiokhimiya, 2010, Vol. 52, No. 2, pp. 165–171.

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Kulyukhin, S.A., Mizina, L.V., Tishina, A.A. et al. Conversion of I2 into ionic species on composite materials in the NPP primary coolant. Radiochemistry 52, 193–200 (2010). https://doi.org/10.1134/S106636221002013X

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  • DOI: https://doi.org/10.1134/S106636221002013X

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