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Crystal structure of the perovskites Ba2AIIUO6 (AII = Zn, Cd, Pb)

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Abstract

The compounds Ba2ZnUO6, Ba2CdUO6, and Ba2PbUO6 were prepared by high-temperature solidphase reactions. Their structures (space group Fm \( \bar 3 \) m) were refined by the Rietveld method. In the morphotropic series Ba2AIIUO6, correlations were found between the AII-O, U-O, and Ba-O bond lengths and the crystal-chemical radius of AII.

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Authors and Affiliations

  1. Lobachevsky Nizhni Novgorod State University, Nizhni Novgorod, Russia

    N. G. Chernorukov, A. V. Knyazev & Z. S. Dashkina

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  1. N. G. Chernorukov
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  2. A. V. Knyazev
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  3. Z. S. Dashkina
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Original Russian Text © N.G. Chernorukov, A.V. Knyazev, Z.S. Dashkina, 2009, published in Radiokhimiya, 2009, Vol. 51, No. 2, pp. 101–103.

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Chernorukov, N.G., Knyazev, A.V. & Dashkina, Z.S. Crystal structure of the perovskites Ba2AIIUO6 (AII = Zn, Cd, Pb). Radiochemistry 51, 116–119 (2009). https://doi.org/10.1134/S1066362209020027

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  • DOI: https://doi.org/10.1134/S1066362209020027

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