Skip to main content
SpringerLink
Log in

Kinetics of bromide ion-isotope exchange with weakly basic macroporous resin Indion-860

  • Published:
Radiochemistry Aims and scope

Abstract

Kinetics of bromide ion-isotope exchange with weakly basic macroporous resin Indion-860 was studied. Two sets of experiments were performed. In the first set, inactive ion-exchange resin samples in the bromide form were equilibrated with a radioactive bromide solution spiked with 82Br tracer, and in the second set of experiments, labeled radioactive ion-exchange resin samples in the bromide form were equilibrated with an inactive bromide solution. The temperature was varied from 25.0 to 40.0°C, and the concentration of bromide ions in solution, from 0.005 to 0.100 M. In separate experiments, performed at a fixed temperature of 25.0°C using 0.0100 M bromide ion solution, the amount of the labeled radioactive ion-exchange resin was varied from 0.250 to 1.000 g. Essentially similar rate constants were obtained for the forward and reverse reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lokhande, R.S., Kolte, A.R., and Prabhavalkar, T.S., Asian J. Chem., 1999, vol. 11, p. 1026.

    CAS  Google Scholar 

  2. Parikh, K., Pandit, B., Padmaja, P., and Chudasama, U., in Technical Bulletin of Anacon-1997 Conf., Mumbai (India), December 1997, p. 19.

  3. Lokhande, R.S. and Tiwari, S.R., Asian J. Chem., 2000, vol. 12, p. 97.

    CAS  Google Scholar 

  4. Lokhande, R.S. and Patil, A.B., Asian J. Chem., 1998, vol. 10, p. 600.

    CAS  Google Scholar 

  5. Chetty, K.V. and Rao, P.R.V., Abstracts of Papers, Nuclear and Radiochemistry Symp., Pune (India), February 2001, p. 246.

  6. Lobo, V., Abstracts of Papers, Nuclear and Radiochemistry Symp., Pune (India), February 2001, p. 406.

  7. Raghupathy, S. and Sudersanan, M., Abstracts of Papers, Nuclear and Radiochemistry Symp., Pune (India), February 2001, pp. 450, 451.

  8. Singh, I.J. and Misra, B.M., Abstracts of Papers, Nuclear and Radiochemistry Symp., Pune (India), February 2001, p. 453.

  9. Choube, U.N., Abstracts of Papers, Nuclear and Radiochemistry Symp., Pune (India), February 2001, p. 467.

  10. Bhatnagar, R.P., Bhardwaj, A., and Bhardwaj, S.D., Asian J. Chem., 1998, vol. 10, pp. 405, 409.

    CAS  Google Scholar 

  11. Bhat, C.V. and Vardia, J., Asian J. Chem., 1998, vol. 10, p. 834.

    CAS  Google Scholar 

  12. Sreenivasan, N.L., Abstracts of Papers, Nuclear and Radiochemistry Symp., Pune (India), February 2001, p. 186.

  13. Lokhande, R.S. and Singare, P.U., Chem. Environ. Res., 1998, vol. 7, nos. 1–2, 3–4, pp. 129, 283.

    CAS  Google Scholar 

  14. Lokhande, R.S. and Singare, P.U., Asian J. Chem., 2000, vol. 12, p. 214.

    CAS  Google Scholar 

  15. Lokhande, R.S. and Singare, P.U., Asian J. Chem., 1999, vol. 11, p. 758.

    CAS  Google Scholar 

  16. Lokhande, R.S. and Singare, P.U., Res. J. Chem. Environ., 1999, vol. 3(3), p. 25.

    CAS  Google Scholar 

  17. Lokhande, R.S. and Singare, P.U., Asian J. Chem., 1998, vol. 10, pp. 898, 1026.

    CAS  Google Scholar 

  18. Lokhande, R.S. and Singare, P.U., Asian J. Chem., 2000, vol. 12, pp. 990, 999, 1003.

    CAS  Google Scholar 

  19. Lokhande, R.S. and Singare, P.U., Orient. J. Chem., 1998, vol. 14, pp. 247, 303.

    CAS  Google Scholar 

  20. Lokhande, R.S. and Singare, P.U., Asian J. Chem., 2001, vol. 13, pp. 8, 13, 20, 43, 50.

    CAS  Google Scholar 

  21. Sawant, S.R. and Mathur, J.N., Abstracts of Papers, Nuclear and Radiochemistry Symp., Pune (India), February 2001, p. 142.

  22. Bonner, O.D., Dickel, G., and Brummer, H., Z. Phys. Chem. (Frankfurt), 1960, vol. 25, p. 81.

    CAS  Google Scholar 

  23. Ekedhal, E., Hogfeldt, E., and Sillen, L.G., Acta. Chem. Scand., 1950, vol. 4, pp. 556, 828, 829.

    Article  Google Scholar 

  24. Helfferich, F., Ion Exchange, New York: McGraw-Hill, 1962, p. 6.

    Google Scholar 

  25. Helfferich, F. and Plasset, M.S., J. Chem. Phys., 1958, vol. 28, p. 418.

    Article  CAS  Google Scholar 

  26. Helfferich, F., J. Phys. Chem., 1962, vol. 66, p. 39.

    Article  CAS  Google Scholar 

  27. Helfferich, F., J. Phys. Chem., 1963, vol. 67, p. 1688.

    Article  Google Scholar 

  28. Dranoff, J.S., Blickenstaff, R.A., and Wanger, J.D., J. Phys. Chem., 1967, vol. 71, p. 1670.

    Article  Google Scholar 

  29. Znamenskii, Yu.P., Kasperovich, A.I., and Bychkov, N.V., Zh. Fiz. Khim., 1962, vol. 36, p. 1060.

    Google Scholar 

  30. Conway, D.E., Green, J.H.S., and Richenberg, D., Disc. Faraday Soc., 1954, vol. 50, p. 511.

    CAS  Google Scholar 

  31. Saldakhmedov, U.A., Rizaev, N.U., and Merenkov, K.V., Massoobm. Prots. Khim. Tekhnol., 1969, no. 4, p. 126.

  32. Ion Exchange and Applications, London: Soc. Chem. Ind., 1958, p. 150.

  33. Madi, I. and Varromagy, T., Kem. Foly., 1972, vol. 78, p. 233.

    CAS  Google Scholar 

  34. Chuveleva, E.A., Nazarov, P.P., and Chmutov, K.V., Zh. Fiz. Khim., 1972, vol. 46, p. 1628.

    Google Scholar 

  35. Bolto, B.A., McNeill, R., Siudak, R., et al., J. Macromol. Sci. Chem., 1970, vol. 4, p. 1039.

    Article  CAS  Google Scholar 

  36. Bolto, B.A. and Warner, R.E., Desalination, 1970, vol. 8, p. 21.

    Article  CAS  Google Scholar 

  37. Saldakhmedov, U.A., Ozhalilov, A.K., Vulikh, A.I., et al., Zh. Prikl. Khim., 1975, vol. 48, p. 2419.

    Google Scholar 

  38. Znamenskii, Yu.P., Kasperovich, A.I., and Bychkov, N.V., Zh. Fiz. Khim., 1968, vol. 42, p. 1586.

    Google Scholar 

  39. Gamayunov, N.I., Zh. Fiz. Khim., 1990, vol. 64, p. 1787.

    Google Scholar 

  40. Tripathi, R. and Ram, K.D., Abstracts of Papers, Radiochemistry and Radiation Chemistry Symp., Kanpur (India), 1985.

  41. Dixit, G.P. and Tripathi, R., Abstracts of Papers, Radiochemistry and Radiation Chemistry Symp., India, 1986.

  42. Lokhande, R.S. and Ingale, M.N., Asian J. Chem., 1999, vol. 11, p. 1034.

    CAS  Google Scholar 

  43. Goswami, A., Abstracts of Papers, Nuclear and Radiochemistry Symp., Pune (India), February 2001, p. 379.

  44. Boyd, G.E., Adamson, A.W., and Myers, L.S., Jr., J. Am. Chem. Soc., 1947, vol. 69, p. 2836.

    Article  CAS  Google Scholar 

  45. Lokhande, R.S., Singare, P.U., and Dole, M.H., Radiochemistry, 2007, vol. 49, no. 5, p. 519.

    Article  CAS  Google Scholar 

  46. Lokhande, R.S., Singare, P.U., and Kolte, A.R., Radiochim. Acta, 2007, vol. 95, no. 10, p. 595.

    Article  CAS  Google Scholar 

  47. Lokhande, R.S. and Singare, P.U., Samyak J. Chem., 1999, vol. 3, p. 24.

    Google Scholar 

  48. Lokhande, R.S. and Singare, P.U., Asian J. Chem., 2003, vol. 15, p. 33.

    CAS  Google Scholar 

  49. Lokhande, R.S. and Singare, P.U., Asian J. Chem., 2005, vol. 17, p. 125.

    CAS  Google Scholar 

  50. Lokhande, R.S. and Singare, P.U., and Patil, A.B., Radiochim. Acta, 2007, vol. 95, no. 1, p. 111.

    Article  CAS  Google Scholar 

  51. Lokhande, R.S. and Singare, P.U., Radiochim. Acta, 2007, vol. 95, no. 3, p. 173.

    Article  CAS  Google Scholar 

  52. Lokhande, R.S., Singare, P.U., and Dole, M.H., J. Nucl. Radiochem. Sci., 2006, vol. 7, no. 2, p. 29.

    CAS  Google Scholar 

  53. Lokhande, R.S., Singare, P.U., and Karthikeyan, P., Russ. J. Phys. Chem. A, 2007, vol. 81, no. 11, p. 1768.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Mumbai, Vidyanagri, Santacruz, Mumbai, 400 098, India

    R. S. Lokhande, P. U. Singare & S. R. D. Tiwari

Authors
  1. R. S. Lokhande
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. U. Singare
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. R. D. Tiwari
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Published in Russian in Radiokhimiya, 2008, Vol. 50, No. 6, pp. 551–554.

The test was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lokhande, R.S., Singare, P.U. & Tiwari, S.R.D. Kinetics of bromide ion-isotope exchange with weakly basic macroporous resin Indion-860. Radiochemistry 50, 633–637 (2008). https://doi.org/10.1134/S106636220806009X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S106636220806009X

PACS numbers

Search

Navigation