Abstract
The kinetics of thermochemical reaction of 30% TBP in hexachlorobutadiene (HCBD) saturated with HNO3 (1.35 M HNO3) in two-phase systems with 12 M HNO3 at temperatures from 90 to 115°C was studied. The kinetic parameters of thermolysis of organic solutions of TBP in HCBD, contacting with HNO3 in open and closed vessels, were determined experimentally for the subsequent estimation of the explosion hazard of these systems under conditions of extraction recovery of high-level radioactive materials. It was shown that, in two-phase systems, solutions of TBP in HCBD exhibit increased resistance to thermochemical oxidation with nitric acid in comparison with hydrocarbon solutions of the extractant in the entire temperature range.
Similar content being viewed by others
References
Egorova, G.F., Afanas’ev, O.P., Nazin, E.R., and Kazarinov, V.E., Radiokhimiya, 1996, vol. 38, no. 6, pp. 531–536.
Belova, E.V., Egorov, G.F., and Nazin, E.R., Radiokhimiya, 2000, vol. 42, no. 3, pp. 238–243.
Nazin, E.R., Zachinyaev, G.M., and Egorov, G.F., Radiokhimiya, 2000, vol. 42, no. 3, pp. 244–246.
Belova, E.V., Egorov, G.F., Nazin, E.R., and Tkhorzhnitskii, G.P., Radiokhimiya, 2001, vol. 43, no. 1, pp. 72–76.
Vladimirova, M.V., Kulikov, I.A., and Kuprii, A.A., At. Energ., 1991, vol. 71, no. 4, pp. 333–337.
Belova, E.V., Egorov, G.F., Nazin, E.R., and Tkhorzhnitskii, G.P., Radiokhimiya, 2002, vol. 44, no. 5, pp. 434–436.
Egorov, G.F., Belova, E.V., Tkhorzhnitskii, G.P., and Tananaev, I.G., Radiokhimiya, 2008, vol. 50, no. 2, pp. 144–146.
Egorov, G.F., Belova, E.V., Tkhorzhnitskii, G.P., et al., Abstracts of Papers, Radiochemical Conf., Dubna, 2006, p. 199.
Author information
Authors and Affiliations
Additional information
Original Russian Text © G.F. Egorov, E.V. Belova, G.P. Tkhorzhnitskii, I.G. Tananaev, E.R. Nazin, G.M. Zachinyaev, 2008, published in Radiokhimiya, 2008, Vol. 50, No. 2, pp. 1473150.
Rights and permissions
About this article
Cite this article
Egorov, G.F., Belova, E.V., Tkhorzhnitskii, G.P. et al. Kinetics of thermochemical reaction of TBP solutions in HCBD with nitric acid in two-phase systems. Radiochemistry 50, 171–175 (2008). https://doi.org/10.1134/S1066362208020148
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1066362208020148