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Synthesis and properties of liquid luminophores POCl3-SbCl5-Nd3+ and POCl3-SbCl5-235UO 2+2

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Luminophores POCl3-SbCl5-Nd3+ with Nd concentration of up to 0.8 M and Nd3+ luminescence lifetime of up to 220 μs and POCl3-SbCl5-235UO 2+2 with uranyl concentration of up to 0.16 M were prepared. It was found that stable liquids POCl3-SbCl5-Nd3+ and POCl3-SbCl5-235UO 2+2 can be obtained when salt crystal hydrates are used or water is added to anhydrous Nd and U(VI) compounds. The SbCl5 content should be 1 ≤ [SbCl5]/[Nd3+] ≤ 2 for the POCl3-SbCl5-Nd3+ system and [SbCl5]/[UO 2+2 ] > 3 for the POCl3-SbCl5-235UO 2+2 system. Based on the solubility of Nd and U(VI) compounds in the POCl3-SbCl5 solvent and spectral-luminescence properties of Nd3+ and UO 2+2 in the luminophores obtained, the following compositions of the complexes formed were suggested: Nd(PO2Cl2)3−y (SbCly)y · xPOCl3, where y = 1, 2, and 3, and UO2(PO2Cl2)(SbCl6) · xPOCl3.

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References

  1. Lapidus, V.I., Dobrovol’skii, A.F., D’yachenko, P.P., et al., Kvant. Elektron., 2003, vol. 33, no. 6, pp. 507–510.

    Article  CAS  Google Scholar 

  2. Batyaev, I.M., Sukhanov, S.B., and Kishalov, F.M., Zh. Prikl. Spektrosk., 1991, vol. 55, no. 3, pp. 507–509.

    CAS  Google Scholar 

  3. Seregina, E.A., Novoderezhkina, T.L., and Kulikovskii, B.N., Zh. Neorg. Khim., 2002, vol. 47, no. 6, pp. 1004–1009.

    CAS  Google Scholar 

  4. Tikhonov, G.V. and Zyatev, V.V., Radiokhimiya, 2002, vol. 44, no. 3, pp. 215–220.

    Google Scholar 

  5. Tikhonov, G.V., Radiokhimiya, 2006, vol. 48, no. 2, pp. 138–140.

    Google Scholar 

  6. Tikhonov, G.V. and Kiselev, S.V., Radiokhimiya, 2006, vol. 48, no. 3, pp. 236–240.

    Google Scholar 

  7. Tikhonov, G.V. and Kiselev, S.V., Radiokhimiya, 2006, vol. 48, no. 5, pp. 394–398.

    Google Scholar 

  8. Seregina, E.A. and Tikhonov, G.V., Khim. Vys. Energ., 2000, vol. 34, no. 1, pp. 30–34.

    Google Scholar 

  9. Tikhonov, G.V., and Seregina, E.A., Abstracts of Papers, XII Simpozium “Sovremennaya khimicheskaya fizika” (XII-th Symp. “Modern Chemical Physics”), Tuapse, September 18–29, 2000, pp. 227–228.

  10. Heller, A., Appl. Phys. Lett., 1966, vol. 8, no. 3, pp. 106–108.

    Article  Google Scholar 

  11. Lempicki, A. and Heller, A., Appl. Phys. Lett., 1966, vol. 8, no. 3, pp. 108–110.

    Article  Google Scholar 

  12. Tikhonov, G.V., Laser-Active Inorganic Liquids, Review of the Inst. of Energy Physics, TsNIIatominform, 1996, no. FEI-0287.

  13. Alekseev, N.E., Gilyarov, O.N., Zhabotinskii, M.E., et al., Izv. Akad. Nauk SSSR, Neorg. Mater., 1969, vol. 5, no. 6, pp. 1038–1041.

    CAS  Google Scholar 

  14. Ivanov, V.M. and Ermakova, N.V., Zh. Anal. Khim., 2001, vol. 56, no. 6, pp. 586–590.

    Google Scholar 

  15. Busev, A.I., Tiptsova, V.G., and Ivanov, V.M., Prakticheskoe rukovodstvo po analiticheskoi khimii redkikh elementov (Practical Handbook on Analytical Chemistry of Less-Common Elements), Moscow: Khimiya, 1966.

    Google Scholar 

  16. Nemodruk, A.A. and Glukhova, L.P., Zh. Anal. Khim., 1963, vol. 18, no. 1, pp. 93–98.

    CAS  Google Scholar 

  17. Korshunov, B.G., Safonov, V.V., and Drobot, D.V., Diagrammy plavkosti khloridnykh system: Spravochnik, (Melting Diagrams of Chloride Systems: Handbook), Leningrad: Khimiya, 1973.

    Google Scholar 

  18. Anikiev, Yu.G. Zhabotinskii, M.E., and Kravchenko, V.B., Lazery na neorganicheskikh zhidkostyakh (Lasers Based on Inorganic Liquids), Moscow: Nauka, 1986.

    Google Scholar 

  19. Brecher, C., and French, K.W., J. Phys. Chem., 1973, vol. 77, no. 11, pp. 1370–1377.

    Article  CAS  Google Scholar 

  20. Kabakov, D.B., and Seregina, E.A., Opt. Spektrosk., 2007, vol. 102, no. 4, pp. 572–577.

    Article  Google Scholar 

  21. Tikhonov, G.V., Radiokhimiya, 1999, vol. 41, no. 2, pp. 112–115.

    Google Scholar 

  22. Kabakov, D.B., Kiselev, S.V., Seregina, E.A., and Tikhonov, G.V., Preprint of the Inst. of Energy Physics, Obninsk, 2004, no. 3040.

  23. Gutmann, V., Coordination Chemistry in Non-Aqueous Solutions, New York: Springer, 1968.

    Google Scholar 

  24. Aslanov, L.A., Gilyarov, O.N., Kulikovskii, B.N., et al., Koord. Khim., 1982, vol. 8, no. 6, pp. 723–736.

    CAS  Google Scholar 

  25. Buchachenko, A.L., and Khudyakov, I.V., Usp. Khim., 1991, vo. 60, no. 6, pp. 1105–1127.

    CAS  Google Scholar 

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  1. Leipunskii Institute of Energy Physics, State Scientific Center of the Russian Federation, Obninsk, Kaluga oblast, Russia

    G. V. Tikhonov & S. V. Kiselev

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  1. G. V. Tikhonov
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  2. S. V. Kiselev
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Original Russian Text © G.V. Tikhonov, S.V. Kiselev, 2007, published in Radiokhimiya, 2007, Vol. 49, No. 6, pp. 524–528.

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Tikhonov, G.V., Kiselev, S.V. Synthesis and properties of liquid luminophores POCl3-SbCl5-Nd3+ and POCl3-SbCl5-235UO 2+2 . Radiochemistry 49, 597–602 (2007). https://doi.org/10.1134/S1066362207060100

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  • DOI: https://doi.org/10.1134/S1066362207060100

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