Abstract
The influence of different agricultural treatments on the contents of Cd, Zn, and Co in the organic matter and humic acids of soddy-podzolic and dark gray forest soils was studied in long-term field experiments. The use of gel chromatography proved the complicated molecular-weight composition of the humic acids in all the studied soils. The contents of heavy metals and their distribution by the molecular-weight fractions of humic acids were determined in the experimental soils and in the virgin podzolic soils. The complex nature of organomineral compounds of Cd and Zn with humic acids was shown by means of gel filtration. The thermodynamic stability of the organomineral complexes increased with the increasing weight of the initial molecular-weight fractions of humic acids.
Similar content being viewed by others
References
L. A. Ermachenko, Atomic Absorption Analysis in Sanitary Studies, Ed. by L. G. Podunova (Chuvashiya, Cheboksary, 1997) [in Russian].
E. G. Zhuravleva, “Trace Elements in Soil Organic Matter,” Pochvovedenie, No. 12, 12–17 (1965).
A. G. Zavarzina, Extended Abstract of Candidate’s Dissertation in Biology (Moscow, 2000).
A. Kabata-Pendias and H. Pendias, Trace Elements in Soils and Plants (CRC, Boca Raton, 1985).
A. I. Karpukhin, Gel Chromatography in Soil Studies (Moscow, 1984) [in Russian].
A. I. Karpukhin and M. E. Kornishina, “Composition and Properties of Organic-Mineral Compounds in the Soils of Vertical Soil-Climatic Zones of Western Pamirs,” Izv. Timiryazevsk. S-Kh. Akad., No. 6, 66–72 (1986).
A. I. Karpukhin and E. M. Kulchaev, “Comparative Gel-Chromatographic Study of Humus Acid Fractions,” Izv. Timiryazevsk. S-Kh. Akad., No. 4, 94–101 (1978).
A. I. Karpukhin, I. G. Platonov, and E. I. Shestakov, “Organic-Mineral Compounds of Podzolic Soils on Calcareous Sandy Loams,” Pochvovedenie, No. 3, 37–45 (1982).
S. V. Kasparov and F. A. Tikhomirov, “Selection of Eluent Systems for Gel Filtration of Humus Acids from Chernozem,” Vestn. Mosk. Univ., Ser. 17: Pochvoved., No. 4, 23–39 (1978).
Methodological Guidelines for the Practical Application of Gel Chromatography to Soil Studies, Ed. by A. I. Karpukhin (Moscow, 1984) [in Russian].
D. S. Orlov and L. A. Grishina, Laboratory Manual on Soil Humus (Mosk. Gos. Univ., Moscow, 1981) [in Russian].
I. O. Plekhanova, O. V. Klenova, and Yu. D. Kutukova, “The Effect of Sewage Sludge on the Content and Fractional Composition of Heavy Metals in Loamy-Sandy Soddy-Podzolic Soils,” Pochvovedenie, No. 4, 496–503 (2001) [Eur. Soil Sci. 34 (4), 440–446 (2001)].
Laboratory Manual on Soil Science, Ed. by I. S. Kaurichev (Agropromizdat, Moscow, 1986) [in Russian].
M. D. Stepanova, Trace Elements in Soil Organic Matter (Novosibirsk, 1976) [in Russian].
S. A. Taldykin, Extended Abstract of Candidate’s Dissertation in Biology (Moscow, 1982).
N. M. Baughman, “The Effect of Organic Matter on the Retention of Zinc by the Soil,” Dissertation Abstracts 16(5), 839 (1956).
C. W. Gray, R. G. McLaren, A. H. C. Robert, et al., “Fractionation of Soil Cadmium from Some New Zealand Soils,” Commun. Soil Sci. Plant Anal. 31(9–10), 1261–1273 (2000).
H. Grimme, “Kupferververteilung in Parabraunerdeprofilen aus Loss,” Z. Pflanzenernaehr. Bodenk-d. 116(2), 125–135 (1967).
G. C. Hazra and P. D. Pattanayak, and Mahdel Biswapati, “Effect of Submergence on the Transformation of Zinc Fractions in Alfisols in Relation to Soil Properties,” J. Indian Soc. Soil Sci. 42(1), 31–36 (1994).
F. L. Himes and S. A. Barber, “Chelating Ability of Soil Organic Matter,” Soil Sci. Soc. Am. Proc. 21(4), 368–373 (1957).
H. Irving and R. J. P. Williams, “Order of Stability of Metal Complexes,” Nature, No. 162, 746–747 (1948).
H. Irving and R. J. P. Williams, “The Stability of Transition Metal Complexes,” J. Chem. Soc., 3192–3210 (1953).
J. O. Onyatta and P. M. Huang, “Chemical Speciation and Bioavailability Index of Cadmium for Selected Tropical Soils in Kenya,” Geoderma 91(1–2), 87–101 (1999).
V. Phogat, D. J. Dahiya, and J. P. Singh, “Effect of Organic Matter and Soil Water Content on the Transformation of Native Soil Zinc,” J. Indian Soc. Soil Sci. 42(2), 239–243 (1994).
I. Rico, J. M. Alvarer, and J. Novillo, “Mobility and Extractability of Zinc in Soil Columns Amended with Micronutrient Formulations,” Commun. Soil Sci. Plant Anal. 26(17–18), 2843–2855 (1995).
R. A. Rossel, A. M. Miglierina, and L. Q. de Novilla, “Stability Constants of Some Complexes of Argentine Humic Acids and Microelements,” in Soil Organic Mater Studies (Vienna, 1977), Vol. 2, pp. 15–21.
F. J. Stevenson, “Nature of Divalent Transition Metal Complexes of Humic Acids as Revealed by a Modified Potentiometric Titration Method,” Soil Sci. 123(1), 10–17 (1977).
T. Takamatsu and T. Yoshida, “Determination of Stability Constants of Metal-Humus Acid Complexes by Potentiometric Titration and Ion-Selective Electrodes,” Soil Sci. 125(6), 377–386 (1978).
D. Wallschlager, M. V. M. Desai, M. Spengler, et al., “How Humic Substances Dominate Mercury Geochemistry in Contaminated Floodplain Soils and Sediments,” J. Environ. Qual. 27(5), 1044–1054 (1998).
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.I. Karpukhin, N.N. Bushuev, 2007, published in Pochvovedenie, 2007, No. 3, pp. 292–301.
Rights and permissions
About this article
Cite this article
Karpukhin, A.I., Bushuev, N.N. Distribution of heavy metals by the molecular-weight fractions of humic acids in the soils of long-term field experiments. Eurasian Soil Sc. 40, 265–273 (2007). https://doi.org/10.1134/S1064229307030040
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1064229307030040