Abstract
The preparation and sonoluminescence of Cr(CO)6 nanodispersed suspensions in water, 83% H2SO4, and 74% H3PO4 are described for the first time. In the spectra of single- and multibubble sonoluminescence of these suspensions, chromium atom lines are found that are analogous to the corresponding lines in the sonoluminescence spectra of true Cr(CO)6 solutions in dodecane. Sonoluminescence of nanodispersed suspensions of metal carbonyl, by which the electronic temperature reached in the bubbles under sonolysis (from 6500 to 16 000 K in water and acids) was measured, expands the scope of the sonochemical model of injection of nanodroplets of low volatile compounds into cavitation bubbles due to the inclusion of injection of suspensions of insoluble substances into it.
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References
F. Grieser, P.-K. Choi, N. Enomoto, H. Harada, K. Okitsu, and K. Yasui, Sonochemistry and the Acoustic Bubble (Elsevier, Amsterdam, 2015).
K. S. Suslick, E. B. Flint, M. W. Grinstaff, and K. A. Kemper, J. Phys. Chem. 97, 3098 (1993).
Y. T. Didenko, W. B. McNamara III, and K. S. Suslick, Phys. Rev. Lett. 84, 777 (2000).
V. A. Borisenok, Acoust. Phys. 61, 308 (2015).
A. A. Ndiaye, R. Pflieger, B. Siboulet, J. Molina, J. F. Dufreche, and S. I. Nikitenko, J. Phys. Chem. A 116, 4860 (2012).
D. J. Flannigan and K. S. Suslick, J. Phys. Chem. Lett. 3, 2401 (2012).
D. J. Flannigan and K. S. Suslick, J. Phys. Chem. B 117, 15886 (2013).
R. Pflieger, T. Ouerhani, T. Belmonte, and S. I. Nikitenko, Phys. Chem. Chem. Phys. 19, 26272 (2017).
H. Xu, N. C. Eddingsaas, and K. S. Suslick, J. Am. Chem. Soc. 131, 6060 (2009).
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Original Russian Text © G.L. Sharipov, B.M. Gareev, A.M. Abdrakhmanov, 2018, published in Pis’ma v Zhurnal Tekhnicheskoi Fiziki, 2018, Vol. 44, No. 23, pp. 52–55.
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Sharipov, G.L., Gareev, B.M. & Abdrakhmanov, A.M. Sonoluminescence of Suspensions of Insoluble Chromium Carbonyl Nanoparticles in Water and Inorganic Acids. Tech. Phys. Lett. 44, 1072–1073 (2018). https://doi.org/10.1134/S1063785018120350
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DOI: https://doi.org/10.1134/S1063785018120350