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Mössbauer study of the magnetic phase composition of single-crystalline rutile (TiO2) implanted with iron ions

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Abstract

Depth-resolved Mössbauer measurements have been performed for four ferromagnetic samples obtained by the implantation of iron ions (enriched to ∼ 50% with 57Fe isotope) into single-crystalline rutile (TiO2) substrates with two crystallographic orientations [(100) and (001)] at different temperatures (300 and 900 K). It is established that the ferromagnetic properties of iron-implanted rutile samples at room temperature are determined by the presence of α-Fe and Fe3O4 phases. The phase composition of samples obtained by iron implantation into substrates heated to 900 K depends on the crystallographic orientation of the substrate, which is explained by a significant anisotropy of the diffusion of iron atoms in rutile.

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Authors and Affiliations

  1. Kazan State University, Kazan, Tatarstan, 420008, Russia

    E. N. Dulov, N. G. Ivoilov, D. M. Khripunov, L. R. Tagirov, R. I. Khaibullin, V. F. Valeev & V. I. Nuzhdin

  2. Zavoisky Physico-Technical Institute, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, 420029, Russia

    E. N. Dulov, N. G. Ivoilov, D. M. Khripunov, L. R. Tagirov, R. I. Khaibullin, V. F. Valeev & V. I. Nuzhdin

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  1. E. N. Dulov
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  2. N. G. Ivoilov
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  3. D. M. Khripunov
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  4. L. R. Tagirov
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  5. R. I. Khaibullin
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  6. V. F. Valeev
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  7. V. I. Nuzhdin
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Correspondence to E. N. Dulov.

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Original Russian Text © E.N. Dulov, N.G. Ivoilov, D.M. Khripunov, L.R. Tagirov, R.I. Khaibullin, V.F. Valeev, V.I. Nuzhdin, 2009, published in Pis’ma v Zhurnal Tekhnicheskoĭ Fiziki, 2009, Vol. 35, No. 11, pp. 1–9.

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Dulov, E.N., Ivoilov, N.G., Khripunov, D.M. et al. Mössbauer study of the magnetic phase composition of single-crystalline rutile (TiO2) implanted with iron ions. Tech. Phys. Lett. 35, 483–486 (2009). https://doi.org/10.1134/S1063785009060017

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