Abstract
The temperature dependence of the dielectric characteristics of metal-containing polymer films obtained using electrochemical polymerization of a Ni(II) complex monomer [NiSalen] have been studied in a temperature interval from 290 to 370 K. The low-frequency polarization characteristics of poly[NiSalen] film samples exhibit a temperature hysteresis. It is suggested that the observed features of a relaxation type are related to reversible transformations of the redox form of the polymer.
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Original Russian Text © V.T. Avanesyan, M.Yu. Puchkov, 2007, published in Pis’ma v Zhurnal Tekhnicheskoĭ Fiziki, 2007, Vol. 33, No. 15, pp. 34–39.