Abstract
The system of modified reception parameters of fibrous piezoactive composites “system of unidirectional ferroelectric crystalline rods–polymer matrix” with 1–3 connectivity is studied in a wide range of volume fractions of the crystalline component. The modified reception parameters are important for estimating the efficiency of harvesting, accumulation, and conversion of energy in a piezoelectric cell at a constant mechanical stress or at a constant strain. Polydomain crystals (1 – x)Pb(Mg1/3Nb2/3)O3–xPbTiO3 (at 0.28 ≤ x ≤ 0.33) and \({\text{L}}{{{\text{i}}}_{{v}}}\)(K1 – yNay\({{)}_{{1 - {v}}}}\)(Nb1 – zTaz)O3:Mn crystals (at \({v}\) = 0.06, y = 0.1–0.3, and z = 0.07–0.17) poled along the [001] crystallographic direction are used as a piezoelectric component. The parameters calculated for 1–3 composites using the matrix method and the effective field method are compared. The role of electromechanical properties of the crystalline component in the formation of the modified reception parameters of composite reception is analyzed. The results of numerical simulation of the effective properties and modified reception parameters associated with them demonstrate the advantages of lead-free 1–3 composite over analogs based on (1 – x)Pb(Mg1/3Nb2/3)O3–xPbTiO3.
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Notes
On account of the weakness of the shear piezoelectric effect as compared with the longitudinal or transverse piezoelectric effect in various 1–3 composites based on FPC or ferroelectric crystals [27], we do not consider RPs \(\lambda _{{15,m}}^{*}\), \(L{\kern 1pt} _{{15}}^{*}\), and so on.
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ACKNOWLEDGMENTS
The authors are grateful to the Russian Foundation for Basic Research for support. Thanks are also due to Prof. A.E. Panich (Southern Federal University) and Prof. C.R. Bowen (University of Bath, United Kingdom) for their unflagging interest in the subject of investigation and fruitful discussions concerning the effectiveness of modern piezoelectric materials. Special thanks are due to Dr. I.A. Parinov (Southern Federal University) and to the reviewer for thorough reading of the manuscript and valuable remarks.
Funding
This study was supported by the Russian Foundation for Basic Research, project no. 20-38-90163.
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Translated by N. Wadhwa
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Topolov, V.Y., Isaeva, A.N. Modified Reception Parameters of 1–3 Composites Based on Ferroelectric Crystals. Tech. Phys. 66, 947–957 (2021). https://doi.org/10.1134/S1063784221060207
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DOI: https://doi.org/10.1134/S1063784221060207