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Investigation of the Hydrogen Etching Effect of the SiC Surface on the Formation of Graphene Films

  • PHYSICS OF LOW-DIMENSIONAL STRUCTURES
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Abstract

We have studied the effect of temperature and etching duration of the 4H-SiC (0001) surface in hydrogen on the structural perfection of graphene films grown by thermal destruction. Several technological modes have been identified that enable etching of the substrate without changing the stoichiometric composition of the surface. It has been demonstrated that pregrowth etching in hydrogen at T = 1600°C with a duration of 1 min makes it possible to obtain a more uniform and structurally perfect graphene than etching at T = 1300°C with a 30 min duration.

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REFERENCES

  1. G. R. Yazdi, T. Iakimov, and R. Yakimova, Crystals 6, 53 (2016). https://doi.org/10.3390/cryst6050053

    Article  Google Scholar 

  2. L. Zhou, V. Audurier, P. Pirouz, and J. A. Powell, J. Electrochem. Soc. 144, 161 (1997).

    Article  Google Scholar 

  3. M. Kumagawa and H. Kuwabara, Jpn. J. Appl. Phys. 8, 421 (1969).

    Article  ADS  Google Scholar 

  4. S. Dogan, D. Johnstone, F. Yun, S. Sabuktagin,   Leach, A. A. Baski, H. Morkoc, G. Li, and B. Ganguly, Appl. Phys. Lett. 85, 1547 (2004). https://doi.org/10.1063/1.1786632

    Article  ADS  Google Scholar 

  5. A. Sagar, C. D. Lee, R. M. Feenstra, C. K. Inoki, and T. S. Kuan, J. Appl. Phys. 92, 4070 (2002). https://doi.org/10.1063/1.1501749

    Article  ADS  Google Scholar 

  6. Ch. L. Frewin, C. C. Colleti, Ch. Riedi, U. Starke, and S. Saddow, Mater. Sci. Forum. 615–617, 589 (2009). https://doi.org/10.4028/www.scientific.net/MSF.615-617.589

    Article  Google Scholar 

  7. R. Anzalone, N. Piluso, M. Salanitri, S. Lorenti, G. Arena, and S. Coffa, Mater. Sci. Forum. 897, 71 (2017). https://doi.org/10.4028/www.scientific.net/MSF.897.71

    Article  Google Scholar 

  8. S. P. Lebedev, I. A. Eliseyev, V. Y. Davydov, A. N. Smirnov, V. S. Levitskii, M. G. Mynbaeva, M. M. Kulagina, B. Hähnlein, J. Pezoldt, and A. A. Lebedev, Tech. Phys. Lett. 43, 849 (2017). https://doi.org/10.1134/S106378501709022X

    Article  ADS  Google Scholar 

  9. A. C. Ferrari, J. C. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K. S. Novoselov, S. Roth, and A. K. Geim, Phys. Rev. Lett. 97, 187401 (2006). https://doi.org/10.1103/PhysRevLett.97.187401

    Article  ADS  Google Scholar 

  10. V. Yu. Davydov, D. Yu. Usachov, S. P. Lebedev, A. N. Smirnov, V. S. Levitskii, I. A. Eliseyev, P. A. Alekseev, M. S. Dunaevskiy, O. Yu. Vilkov, A. G. Rybkin, and A. A. Lebedev, Semiconductors 51, 1072 (2017). https://doi.org/10.1134/S1063782617080073

    Article  ADS  Google Scholar 

  11. V. Panchal, R. Pearce, R. Yakimova, A. Tzalenchuk, and O. Kazakova, Sci. Rep. 3, 2597 (2013). https://doi.org/10.1038/srep0259

    Article  ADS  Google Scholar 

  12. F. Fromm, M. H. Oliveira, Jr., A. Molina-Sánchez,   M. Hundhausen, J. M. J. Lopes, H. Riechert, L. Wirtz, and T. Seyller, New J. Phys. 15, 043031 (2013). https://doi.org/10.1088/1367-2630/15/4/043031

    Article  ADS  Google Scholar 

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Funding

The study was supported by the Ministry of Science and Education of the Russian Federation (Agreement no. 14.575.21.0148, unique project no. RFMEFI57517X0148).

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Correspondence to S. P. Lebedev.

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The authors declare that they do not have any conflicts of interest.

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Translated by G. Dedkov

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Lebedev, S.P., Barash, I.S., Eliseyev, I.A. et al. Investigation of the Hydrogen Etching Effect of the SiC Surface on the Formation of Graphene Films. Tech. Phys. 64, 1843–1849 (2019). https://doi.org/10.1134/S1063784219120144

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  • DOI: https://doi.org/10.1134/S1063784219120144

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