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Low-temperature nanodoping of protonated LiNbO3 crystals by univalent ions

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Abstract

In the nanocomposite model developed here, crystals are treated as subordinate aggregate of pro- ton-selected structural elements, their blocks, and proton-containing quantum sublattices with preferred transport effects separating them. The formation of stratified reversible hexagonal structures is accompanied with protonation and formation of a dense network of H-bonds ensuring the nanocomposite properties. Nanodoping with H+ ions occurs during processing of crystals and glasses in melts as well as in aqueous solutions of Ag, Tl, Rb, and Cs salts. The isotope exchange H+ ↔ D+ and ion exchange H+ ↔ M+ lead to nanodoping of protonated materials with D+ and M+ ions. This is manifested especially clearly in Li-depleted nonequilibrium LiNbO3 and LiTaO3 crystals. Low-temperature proton-ion nanodoping over superlattices is a basically new approach to analysis of the structure and properties of extremely nonequilibrium materials.

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Authors and Affiliations

  1. National Research Tomsk Polytechnic University, pr. Lenina 30, Tomsk, 634050, Russia

    Yu. V. Borodin

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  1. Yu. V. Borodin
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Correspondence to Yu. V. Borodin.

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Original Russian Text © Yu.V. Borodin, 2015, published in Zhurnal Tekhnicheskoi Fiziki, 2015, Vol. 85, No. 1, pp. 109–113.

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Borodin, Y.V. Low-temperature nanodoping of protonated LiNbO3 crystals by univalent ions. Tech. Phys. 60, 107–111 (2015). https://doi.org/10.1134/S1063784215010065

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