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Synthesis, Crystal Structure, and Thermal Properties of Substituted Titanates Bi2Pr2Ti3O12 and Bi2Nd2Ti3O12

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Abstract

Titanates Bi2Pr2Ti3O12 and Bi2Nd2Ti3O12 have been obtained by the solid-phase synthesis using sequential annealing of the Bi2O3, Nd2O3, Pr6O11, and TiO2 stoichiometric mixtures in air at temperatures of 1003–1323 K. Their crystal structure has been established by X-ray diffractometry and the high-temperature heat capacity has been determined by differential scanning calorimetry. Based on the experimental Cp = f(T) data, the main thermodynamic functions have been calculated.

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ACKNOWLEDGMENTS

The authors thank the Krasnoyarsk Territorial Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch of the Russian Academy of Sciences.

Funding

This study was carried out in part within the state assignment for the Siberian Federal University, project no. FSRZ-2020-0013.

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Authors and Affiliations

  1. Siberian Federal University, 660041, Krasnoyarsk, Russia

    L. T. Denisova, M. S. Molokeev, N. A. Galiakhmetova, V. M. Denisov & G. V. Vasil’ev

  2. Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

    M. S. Molokeev

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  1. L. T. Denisova
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  2. M. S. Molokeev
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  3. N. A. Galiakhmetova
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Correspondence to L. T. Denisova.

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Translated by E. Bondareva

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Denisova, L.T., Molokeev, M.S., Galiakhmetova, N.A. et al. Synthesis, Crystal Structure, and Thermal Properties of Substituted Titanates Bi2Pr2Ti3O12 and Bi2Nd2Ti3O12. Phys. Solid State 63, 1159–1164 (2021). https://doi.org/10.1134/S1063783421080084

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  • DOI: https://doi.org/10.1134/S1063783421080084

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