Abstract
Trigonal neodymium scandoborate NdSc3(BO3)4 single crystals have been grown by the batch flux method using bismuth trimolybdate and their magnetic and magnetoelectric properties have been investigated in the temperature range of 4.2–300 K in magnetic fields of up to 9 T. Magnetically, the compound is a paramagnet and its properties are determined by the magnetic properties of the Nd3+ ion with allowance for the Van Vleck paramagnetic correction. The magnetoelectric polarization value has been found to be comparable with that of the previously investigated diluted neodymium aluminum borate Nd0.35Y0.65Al3(BO3)4. The latter circumstance opens up another subclass of compounds that should exhibit the giant magnetoelectric effect.
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Funding
This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk krai, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 18-42-240011 “Development of the Flux Techniques for Growing New Scandoborate Single Crystals with a Huntite Structure and Study of the Interaction of Their Magnetic and Electric Subsystems.”
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Translated by E. Bondareva
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Eremin, E.V., Dubrovskii, A.A., Gudim, I.A. et al. Magnetic and Magnetoelectric Properties of Scandoborate NdSc3(BO3)4. Phys. Solid State 63, 968–971 (2021). https://doi.org/10.1134/S1063783421070052
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DOI: https://doi.org/10.1134/S1063783421070052