Skip to main content
Log in

On the Contact of a Two-Dimensional Transition Metal with a Graphene-Like Compound

  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

In terms of a simple model, analytical expressions for the charge transition and Schottky barrier height at the contact of a two-dimensional d-metal with a ANB8 – N graphene-like compound have been obtained. It has been shown that the metal two-dimensionality can be taken into account by means of narrowing its d-band. By the examples of the Gr–2DM and hBN–2DM systems, it has been demonstrated that the proposed approach leads to satisfactory results.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. A. K. Geim and K. S. Novoselov, Nat. Mater. 6, 183 (2007).

    Article  ADS  Google Scholar 

  2. A. K. Geim and I. V. Grigorieva, Nature (London, U.K.) 499, 419 (2013).

    Article  Google Scholar 

  3. C.-J. Tong, H. Zhang, Y.-N. Zhang, H. Liu, and L.‑M. Liu, J. Mater. Chem. A 2, 17971 (2014).

    Article  Google Scholar 

  4. S. Haastrup, M. Strange, M. Pandey, T. Deilmann, P. S. Schmidt, N. F. Hinsche, M. N. Gjerding, D. Torelli, P. M. Larsen, A. C. Riis-Jensen, J. Gath, K. W. Jacobsen, J. J. Mortensen, T. Olsen, and K. S. Thygesen, 2D-Mater. 5, 042002 (2018).

  5. L. Vannucci, U. Petralanda, A. Rasmussen, T. Olsen, and K. S. Thygesen, arXiv: 2007.04152.

  6. N. Briggs, S. Subramanian, Z. Lin, X. Li, X. Zhang, K. Zhang, K. Xiao, D. Geohegan, R. Wallace, L.‑Q. Chen, M. Terrones, A. Ebrahimi, S. Das, J. Redwing, C. Hinkle, K. Momeni, A. van Duin, V. Crespi, S. Kar, and J. A. Robinson, 2D-Mater. 6, 022001 (2019).

  7. J. Nevalaita and P. Koskinen, Phys. Rev. B 97, 035411 (2018).

    Article  ADS  Google Scholar 

  8. J. Nevalaita and P. Koskinen, AIP Adv. 10, 065327 (2020).

    Article  ADS  Google Scholar 

  9. S. Ono, arXiv: 2007.06774.

  10. S. Ono, Sci. Rep. 10, 11810 (2020).

    Article  ADS  Google Scholar 

  11. T. Wang, M. Park, Q. Yu, J. Zhang, and Y. Yang, Mater. Today Adv. 8, 100092 (2020).

    Article  Google Scholar 

  12. S. Yu. Davydov, Phys. Solid State 58, 804 (2016).

    Article  ADS  Google Scholar 

  13. T. Ando, A. B. Fowler, and F. Stern, Rev. Mod. Phys. 54, 438 (1982).

    Article  ADS  Google Scholar 

  14. W. A. Harrison, The Electronic Structure and Properties of Solids (Freeman, San Francisco, CA, 1980), Chap. 20.

    Google Scholar 

  15. Ch. Kittel, Introduction to Solid State Physics (Wiley, New York, 1996), Chap. 18.

    MATH  Google Scholar 

  16. T. Bechshtedt and R. Enderlein, Semiconductor Surfaces and Interfaces. Their Atomic and Electronic Structures (Akademie, Berlin, 1988), Chap. 4.

    Google Scholar 

  17. I. V. Antonova, Semiconductors 50, 66 (2016).

    Article  ADS  Google Scholar 

  18. W. Xia, L. Dai, P. Yu, X. Tong, W. Song, G. Zhang, and Z. Wang, Nanoscale 9 4324 (2017). https://doi.org/10.1039/c7nr00844a

    Article  Google Scholar 

  19. R. T. Tung, Appl. Phys. Rev. 1, 011304 (2014).

    Article  ADS  Google Scholar 

  20. D. S. Schulman, A. J. Arnold, and S. Das, Chem. Soc. Rev. 47, 3037 (2018).

    Article  Google Scholar 

  21. H. Huang, W. Xu, T. Chen, R.-J. Chang, Y. Sheng, Q. Zhang, L. Hou, and J. H. Warner, ACS Appl. Mater. 10, 37258 (2018).

    Google Scholar 

  22. J.-H. Kim, J. H. Hwang, J. Suh, S. Tongay, S. Kwon, C. C. Hwang, J. Wu, and J. Y. Park, Appl. Phys. Lett. 103, 171604 (2013).

    Article  ADS  Google Scholar 

  23. D. Niesner and T. Fauster, J. Phys.: Condens. Matter 26, 393001 (2014).

    Google Scholar 

  24. S. Thomas, M. S. Manju, K. M. Ajith, S. U. Lee, and M. A. Zaeem, Phys. E (Amsterdam, Neth.) 123, 114180 (2020).

  25. R. Roldarn, L. Chirolli, E. Prada, J. A. Silva-Guillern, P. San-Jose, and F. Guinea, Chem. Soc. Rev. 46, 4387 (2017).

    Article  Google Scholar 

  26. Z.-Q. Xu, N. Mendelson, J. A. Scott, C. Li, I. Aharonovich, and M. Tothz, arXiv: 1907.00471.

  27. C. Kimura, K. Okada, S. Funakawa, S. Sakata, and T. Sugino, Diamond Rel. Mater. 14, 719 (2005).

    Article  ADS  Google Scholar 

  28. Ch. Kittel, Introduction to Solid State Physics (Wiley, New York, 1996), Chap. 1.

    MATH  Google Scholar 

  29. V. S. Fomenko, Emission Properties of Materials (Naukova Dumka, Kiev, 1981) [in Russian].

    Google Scholar 

  30. P. A. Khomyakov, G. Giovannetti, P. C. Rusu, G. Brocks, J. van den Brink, and P. J. Kelly, Phys. Rev. B 79, 195425 (2009).

    Article  ADS  Google Scholar 

  31. L. Kong, C. Bjelkevig, S. Gaddam, M. Zhou, Y. H. Lee, G. H. Han, H. K. Jeong, N. Wu, Z. Zhang, J. Xiao, P. A. Dowben, and J. A. Kelber, J. Phys. Chem. C 114, 21618 (2010).

    Article  Google Scholar 

  32. Handbook of Physical Quantities, Ed. by I. S. Grigoriev and E. Z. Meilikhov (Energoatomizdat, Moscow, 1991; CRC, Boca Raton, NY, 1996).

  33. D. C. Elias, R. V. Gorbachev, A. S. Mayorov, S. V. Morozov, A. A. Zhukov, P. Blak, L. A. Ponomarenko, I. V. Grigorieva, K. S. Novoselov, F. Guinea, and A. K. Geim, Nat. Phys. 7, 701 (2011).

    Article  Google Scholar 

  34. R. Bessler, U. Duerig, and E. Koren, Nanoscale Adv. 1, 1702 (2019).

    Article  ADS  Google Scholar 

  35. S. Yu. Davydov, A. A. Lebedev, and O. V. Posrednik, An Elementary Introduction to the Theory of Nanosystems (Lan’, St. Petersburg, 2014), Chap. 9 [in Russian].

  36. S. Yu. Davydov, Semiconductors 47, 95 (2013).

    Article  ADS  Google Scholar 

  37. S. Yu. Davydov and S. V. Troshin, Phys. Solid State 49, 759 (2007).

    Article  ADS  Google Scholar 

  38. M. Bokdam, G. Brocks, M. I. Katsnelson, and P. J. Kelly, Phys. Rev. B 90, 085415 (2014).

    Article  ADS  Google Scholar 

  39. A. Abdelhafiz, A. Vitale, P. Buntin, B. deGlee, C. Joiner, A. Robertson, E. M. Vogel, J. Warner, and F. M. Alamgir, Energy Environ. Sci. 11, 1610 (2018).

    Article  Google Scholar 

  40. G. Zhou, Phys. Chem. Chem. Phys. 22, 667 (2020).

    Article  Google Scholar 

  41. S. Forti, S. Link, A. Stöhr, Y. Niu, A. A. Zakharov, C. Coletti, and U. Starke, Nat. Commun. 11, 2236 (2020).

    Article  ADS  Google Scholar 

  42. N. Briggs, B. Bersch, Y. Wang, J. Jiang, R. J. Koch, N. Nayir, K. Wang, M. Kolmer, W. Ko, A. de la Fuente Duran, S. Subramanian, C. Dong, J. Shallenberger, M. Fu, Q. Zou, et al., Nat. Mater. 19, 637 (2020).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. Yu. Davydov.

Ethics declarations

The author declares that he has no conflicts of interest.

Additional information

Translated by E. Smirnova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Davydov, S.Y. On the Contact of a Two-Dimensional Transition Metal with a Graphene-Like Compound. Phys. Solid State 63, 796–801 (2021). https://doi.org/10.1134/S1063783421060044

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063783421060044

Keywords:

Navigation