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NaSrBO3:Ce,Yb Phosphor for NIR Emission around 1 μm

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Abstract

Synthesis and characterization of NaSrBO3:Ce,Yb phosphor is described. NaSrBO3:Ce phosphor exhibited characteristic Ce3+ emission around 414 nm. Co-doping with Yb3+ resulted in near-infrared (NIR) emission around 981 nm. This is attributed to phonon-assisted cooperative energy transfer from Ce3+ to two Yb3+ ions. Ce3+ → Yb3+ energy transfer is proved using a variety of measurements such as dependence of photoluminescence intensity of visible and NIR emissions on Yb3+ concentration, excitation spectrum for Yb3+, accelerated decay of Ce3+ emission after Yb3+ codoping, etc. Using lifetime measurements, the efficiency of Ce3+ → Yb3+ energy transfer is estimated to be 48.65%.

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ACKNOWLEDGMENTS

Unit cell of alpha NaSrBO3 (Fig. 2) is drawn using Vesta software. We are thankful to the developers [36] for free use.

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Authors and Affiliations

  1. Department of Physics, Jagadamba Mahavidyalaya Achalpur City, 444806, Achalpur, India

    P. K. Tawalare

  2. Shri Ramdeobaba College of Engineering and Management, 440013, Nagpur, India

    P. D. Belsare

  3. Department of Physics, Rashtrasant Tukadoji Maharaj Nagpur University, 440033, Nagpur, India

    S. V. Moharil

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  1. P. K. Tawalare
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Correspondence to P. K. Tawalare.

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Tawalare, P.K., Belsare, P.D. & Moharil, S.V. NaSrBO3:Ce,Yb Phosphor for NIR Emission around 1 μm. Phys. Solid State 63, 758–763 (2021). https://doi.org/10.1134/S1063783421050176

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