Abstract
An analysis of primary literature sources shows that there is only one reliable report on the observation of the cubic ZrO2 phase by the X-ray method under oxidizing conditions. This phase is observed at temperatures not lower than 2500°C. All other reports on the observation of a phase transition around 2300°C are reliable only in relation to the existence of a transition at this temperature, but this transition is to the t' tetragonal phase rather than to the cubic one. The conclusion is that the following four polymorphic modifications are present in ZrO2 under the standard pressure: monoclinic (m), two tetragonal (t and t'), and cubic (c) phases that are converted into each other with an increase in the temperature.
Similar content being viewed by others
REFERENCES
E. R. Andrievskaya, J. Eur. Ceram. Soc. 28, 2363 (2008).
M. Yashima, M. Kakihana, and M. Yoshimura, Solid State Ionics 86–88, 1131 (1996).
T. Liu, X. Zhang, X. Wang, J. Yu, and L. Li, Ionics 22, 2249 (2016).
T. Noguchi, T. Okubo, and O. Yonemochi, J. Am. Ceram. Soc. 52, 178 (1969).
V. P. Gorelov, Tr. Inst. Elektrokhim. UNTs ANSSSR 26, 69 (1978).
State Diagrams of Refractory Oxide Systems: A Handbook, No. 5: Binary systems, Ed. by F. Ya. Galakhov (Nauka, Leningrad, 1985), Part 1 [in Russian].
D. K. Smith and C. F. Cline, J. Am. Ceram. Soc. 45, 249 (1962).
G. M. Wolten, J. Am. Ceram. Soc. 46, 418 (1963).
A. G. Boganov, V. S. Rudenko, and L. P. Makarov, Dokl. Akad. Nauk SSSR 160, 1065 (1965).
J. Hubert, Rev. Int. Hautes. Temper. Refract. 11, 253 (1974).
V. S. Stubican and S. P. Ray, J. Am. Ceram. Soc. 60, 534 (1977).
P. Aldebert and J. P. Traverse, J. Am. Ceram. Soc. 68, 34 (1985).
C. Ruff and F. Ebert, Z. Anorg. Allgem. Chem. 180, 19 (1929).
T. H. Etsell and S. N. Flengas, Chem. Rev. 70, 339 (1970).
P. S. Duwez, F. N. Brown, and F. Odell, J. Electrochem. Soc. 98, 356 (1951).
J. Lefevre, Ann. Chim. 8, 117 (1963).
R. Ruh, H. J. Garrett, R. F. Domagala, and V. A. Patel, J. Am. Ceram. Soc. 60, 399 (1977).
J. A. Krogstad, S. Kramer, D. M. Lipkin, C. A. Johnson, D. R. G. Mitchell, J. M. Cairney, and C. G. Levi, J. Am. Ceram. Soc. 94, S168 (2011).
I. V. Mazilin, L. Kh. Baldaev, D. V. Drobot, E. Yu. Mar-chukov, and N. G. Zaitsev, Inorg. Mater. 52, 802 (2016).
S. V. Ushakov and A. Navrotsky, J. Am. Ceram. Soc. 95, 1463 (2012).
T. Noguchi, M. Mizuno, and T. Yamada, Bull. Chem. Soc. Jpn. 43, 2614 (1970).
A. Rouanet, C.R. Acad. Sci. Paris C 267, 1581 (1968).
K. K. Srivastava, R. N. Patil, C. B. Choudhary, K. V. G. K. Gokhale, and E. C. Subbarao, Trans. J. Brit. Ceram. Soc. 73, 85 (1974).
H. G. Scott, J. Mater. Sci. 10, 1527 (1975).
S. A. Ghyngazov, I. P. Vasil’ev, A. P. Surzhikov, T. S. Frangulyan, and A. V. Chernyavskii, Tech. Phys. 60, 128 (2015).
A. Revcolevschi, Rev. Int. Hautes Temp. Refract. 7, 73 (1970).
R. A. Evarestov and Yu. E. Kitaev, J. Appl. Cryst. 49, 1572 (2016).
Y. Suzuki, Solid State Ionics 81, 211 (1995).
V. P. Gorelov, in Proceedings of the International Conference on Intellectual Technologies in Power Engineering (Physical Chemistry and Electrochemistry of Molten and Solid Electrolytes) (Azhur, Yekaterinburg, 2017), p. 190.
O. A. Graeve, in Ceramic and Glass Materials: Structure, Properties and Processing (Springer, New York, 2008), p. 169.
ACKNOWLEDGMENTS
I am grateful to A.V. Kuz’min and V.B. Balakireva for their valuable comments and assistance in this study.
Funding
This work was partly supported by the Russian Foundation for Basic Research (grant no. 17-08-01227).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Kadkin
Rights and permissions
About this article
Cite this article
Gorelov, V.P. High-Temperature Phase Transitions in ZrO2. Phys. Solid State 61, 1288–1293 (2019). https://doi.org/10.1134/S1063783419070096
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063783419070096