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Study of the Physical Properties and Electrocaloric Effect in the BaTiO3 Nano- and Microceramics

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Abstract

The specific heat, thermal expansion, permittivity, and electrocaloric effect in bulk of BaTiO3 (BT) samples in the form of nano- (nBT-500 nm) and micro- (mBT-1200 nm) ceramics fabricated using spark plasma sintering and solid-state plasma techniques have been investigated. The size effect has been reflected, to a great extent, in the suppression of the specific heat and thermal expansion anomalies and in the changes in the temperatures and entropies of phase transitions and permittivity, and a decrease in the maximum intensive electrocaloric effect: \(\Delta T_{{{\text{AD}}}}^{{\max }}\) = 29 mK (E = 2.0 kV/cm) for nBT and \(\Delta T_{{{\text{AD}}}}^{{\max }}\) = 70 mK (E = 2.5 kV/cm) for mBT. The conductivity growth at temperatures above 360 K leads to the significant irreversible heating of the samples due to the Joule heat release in the applied electric field, which dominates over the electrocaloric effect.

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Authors and Affiliations

  1. Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

    A. V. Kartashev, V. S. Bondarev, I. N. Flerov, M. V. Gorev, E. I. Pogorel’tsev, A. V. Shabanov & M. S. Molokeev

  2. Krasnoyarsk State Pedagogical University, 660049, Krasnoyarsk, Russia

    A. V. Kartashev

  3. Siberian Federal University, Institute of Engineering Physics and Radio Electronics, 660041, Krasnoyarsk, Russia

    V. S. Bondarev, I. N. Flerov, M. V. Gorev, E. I. Pogorel’tsev & M. S. Molokeev

  4. CIRIMAT Laboratory, University of Toulouse, 31062, Toulouse, France

    S. Guillemet-Fritsch

  5. Southern Federal University, Research Institute of Physics, 344090, Rostov-on-Don, Russia

    I. P. Raevskii

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  1. A. V. Kartashev
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  2. V. S. Bondarev
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  3. I. N. Flerov
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  4. M. V. Gorev
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  5. E. I. Pogorel’tsev
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  6. A. V. Shabanov
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  7. M. S. Molokeev
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  8. S. Guillemet-Fritsch
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Correspondence to A. V. Kartashev.

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Translated by E. Bondareva

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Kartashev, A.V., Bondarev, V.S., Flerov, I.N. et al. Study of the Physical Properties and Electrocaloric Effect in the BaTiO3 Nano- and Microceramics. Phys. Solid State 61, 1052–1061 (2019). https://doi.org/10.1134/S1063783419060088

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  • DOI: https://doi.org/10.1134/S1063783419060088

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