Abstract
The aqueous solutions of different stability containing silver sulfide (Ag2S) nanoparticles are studied. The stable, transparent, and turbid solutions have been subjected to daylight for 7 months, to ultraviolet and laser irradiation, as well as to an electron beam. Solar radiation is found to favor the Ag2S reduction to Ag and/or the formation of Ag2S/Ag hybrid nanoparticles in the solution. At a high amount of hybrid nanoparticles, the exciton–plasmon interaction causes asymmetry in the absorption spectra. The exposure of Ag2S particles precipitated from the solution with the electron beam leads to the reversible growth of Ag threads. The possible exciton–plasmon interplay mechanisms in Ag2S/Ag hybrid nanoparticles are considered. The physical mechanisms of the changing Ag2S stoichiometry, the formation of metallic Ag and Ag2S/Ag hybrid nanoparticles are the generation of hot carriers and the energy transfer (exciton–plasmon interaction) in a metal–semiconductor hybrid nanosystem are elucidated, as well.
Similar content being viewed by others
References
M. L. Brongersma, N. J. Halas, and P. Nordlander, Nat. Nanotechnol. 10, 25 (2015).
Q. Li, H. Wei, and H. Xu, Nano Lett. 14, 3358 (2014).
X.-C. Ma, Y. Dai, L. Yu, and B.-B. Huang, Light: Sci. Appl. 5, e16017 (2016).
A. O. Govorov and H. H. Richardson, Nano Today 2, 30 (2007).
E. Khon, A. Mereshchenko, A. N. Tarnovsky, K. Acharya, A. Klinkova, N. N. Hewa-Kasakarage, I. Nemitz, and M. Zamkov, Nano Lett. 11, 1792 (2011).
J-Y. Yan, W. Zhang, S. Duan, X.-G. Zhao, and A. O. Govorov, Phys. Rev. B 77, 165301 (2008).
W. R. Erwin, H. F. Zarick, E. M. Talbert, and R. Bardhan, Energy Environ. Sci. 9, 1577 (2016).
P. Narang, R. Sundararaman, and H. A. Atwater, Nanophotonics 5, 96 (2016).
H. Zhang, V. Kulkarni, E. Prodan, P. Nordlander, and A. O. Govorov, J. Phys. Chem. C 118, 16035 (2014).
E.-M. Roller, L. Khosravi Khorashad, M. Fedoruk, R. Schreiber, A. O. Govorov, and T. Liedl, Nano Lett. 15, 1368 (2015).
T. Bora, D. Zoepfl, and J. Dutta, Sci. Rep. 6, 26913 (2016).
J. Yang, N. J. Kramer, K. S. Schramke, L. M. Wheeler, L. V. Besteiro, C. J. Hogan, Jr. A. O, Govorov, and U. R. Kortshagen, Nano Lett. 16, 1472 (2016).
G. Zhu and Z. Xu, J. Am. Chem. Soc. 133, 148 (2011).
K. Terabe, T. Nakayama, T. Hasegawa, and M. Aono, J. Appl. Phys. 91, 10110 (2002).
L. Motte and J. Urban, J. Phys. Chem. B 109, 21499 (2005).
V. I. Roldugin, Russ. Chem. Rev. 69, 821 (2000).
N. Satoh, H. Hasegawa, and K. Tsujii, J. Phys. Chem. 98, 2143 (1994).
S. I. Sadovnikov, A. I. Gusev, E. Yu. Gerasimov, and A. A. Rempel, Chem. Phys. Lett. 642, 17 (2015).
S. I. Sadovnikov, A. I. Gusev, and A. A. Rempel, Nano-Struct. Nano-Objects 7, 81 (2016).
B. E. Dahneke, Measurement of Suspended Particles by Quasielastic Light Scattering (Wiley, New York, 1983).
R. Pecora, Dynamic Light Scattering: Applications of Photoncorrelation Spectroscopy (Springer, New York, 1985).
M. Kaszuba, D. McKnight, M. T. Connah, F. C. McNeil-Watson, and U. J. Nobbmann, Nanopart. Res. 10, 823 (2008).
W. Tscharnuter, in Encyclopedia of Analytical Chemistry, Ed. by R. A. Meyers (Wiley, New York, 2000), p. 5469.
R. J. Hunter, Zeta Potential in Colloid Science: Principles and Applications (Academic, 1988).
V. V. Kuznetsov, Physical and Colloid Chemistry (Vyssh. Shkola, Moscow, 1968) [in Russian].
C. Li, Y. Zhang, M. Wang, Y. Zhang, G. Chen, L. Li, D. Wu, and Q. Wang, Biomaterials 35, 393 (2014).
M. Yarema, S. Pichler, M. Sytnyk, R. Seyrkammer, R. Lechner, G. Popovski, D. Jarzab, K. Szendrei, R. Resel, O. Korovyanko, M. Loi, O. Paris, G. Hesser, and W. Heiss, ACS Nano 5, 3758 (2011).
W. Zhang, A. O. Govorov, and G. W. Bryant, Phys. Rev. Lett. 97, 146804 (2006).
V. G. Rivera, F. A. Ferri, and E. Marega, Jr., in Plasmonics: Principles and Applications, Ed. by K. Y. Kim (InTech, Rijeka, Croatia, 2012), Chap. 11.
X. M. Wu, P. L. Redmond, H. T. Liu, Y. H. Chen, M. Steigerwald, and L. Brus, J. Am. Chem. Soc. 130, 9500 (2008).
R. Jin, Y. C. Cao, E. Hao, G. S. Métraux, G. C. Schatz, and C. A. Mirkin, Nature 425, 487 (2003).
J. Lee, P. Hernandez, J. Lee, A. O. Govorov, and N. A. Kotov, Nat. Mater. 6, 291 (2007).
A. E. Miroshnichenko, S. V. Mingaleev, S. Flach, and Y. S. Kivshar, Phys. Rev. E 71, 036626 (2005).
A. O. Govorov and H. Zhang, J. Phys. Chem. C 119, 6181 (2015).
S. V. Rempel’, N. N. Aleksandrova, Yu. V. Kuznetsova, and E. Yu. Gerasimov, Inorg. Mater. 52, 101 (2016).
S. Linic, P. Hristopher, and D. B. Ingram, Nat. Mater. 10, 911 (2011).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.V. Rempel, Yu.V. Kuznetsova, E.Yu. Gerasimov, A.A. Rempel’, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 8, pp. 1604–1611.
Rights and permissions
About this article
Cite this article
Rempel, S.V., Kuznetsova, Y.V., Gerasimov, E.Y. et al. The irradiation influence on the properties of silver sulfide (Ag2S) colloidal nanoparticles. Phys. Solid State 59, 1629–1636 (2017). https://doi.org/10.1134/S1063783417080224
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063783417080224