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Rubidium-cation conductivity of Rb3–2x Pb x PO4 solid solutions

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Abstract

New Rb3PO4-based ceramic materials with high rubidium-cation conductivity in the Rb3–2x Pb x PO4 system have been synthesized and studied. Introduction of Pb2+ cations leads to a sharp increase in the conductivity of rubidium orthophosphate due to formation of cation vacancies and, at temperatures 350–550°C, also due to the stabilization of high-temperature cubic modification Rb3PO4. At high temperatures, the electrolytes prepared have very high ion conductivity higher than 10–1 S cm–1 at 700°C, which is higher than the values previously obtained in similar systems with additions of tin and cadmium ions. The factors influencing the transport properties of the materials under study are discussed.

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Authors and Affiliations

  1. Institute of High Temperature Electrochemistry, Ural Branch of the Russian Academy of Sciences, ul. Akademicheskaya 20, Yekaterinburg, 620990, Russia

    G. Sh. Shekhtman & E. I. Burmakin

Authors
  1. G. Sh. Shekhtman
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  2. E. I. Burmakin
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Correspondence to G. Sh. Shekhtman.

Additional information

Original Russian Text © G.Sh. Shekhtman, E.I. Burmakin, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 7, pp. 1350–1354.

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Shekhtman, G.S., Burmakin, E.I. Rubidium-cation conductivity of Rb3–2x Pb x PO4 solid solutions. Phys. Solid State 59, 1377–1381 (2017). https://doi.org/10.1134/S1063783417070265

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