Skip to main content
Log in

Preparation and investigation of soluble functionalized polyanilines

  • Polymers
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

Soluble electron-donor conducting (co)polymers based on functionalized monomeric anilines have been synthesized and characterized for the first time. It has been shown that there is a good correlation between the results obtained from investigations of the electrochemical properties of polyaniline derivatives by the methods of cyclic voltammetry and on the basis of the temperature dependence of the electrical conductance. The polymer based on 2-(1-methyl-2-buten-1-yl)aniline has the lowest energy level of the highest occupied molecular orbital, which determines the prospects for its use as a donor in the active layer when designing organic solar cells.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. R. Blythe and D. Bloor, Electrical Properties of Polymers (Cambridge University Press, New York, 2005, Fizmatlit, Moscow, 2008).

    Google Scholar 

  2. N. E. Kazantseva, in Polymer Composites, Ed. by Sabu Thomas, Kuruvilla Joseph, Sant Kumar Malhotra, Koichi Goda, and Meyyarappallil Sadasivan Sreekala (Willey, Weinheim, 2012), Vol. 1, p. 613.

    Book  Google Scholar 

  3. I. I. Zyat’kov, A. I. Maksimov, and V. A. Moshnikov, Sensors Based on Field-Effect Transistors (St. Petersburg Electrotechnical University “LETI,” St. Petersburg, 2002) [in Russian].

    Google Scholar 

  4. H. Bai and G. Shi, Sensors, 7 (3), 267 (2007).

    Article  Google Scholar 

  5. V. E. Bochenkov and V. G. Sergeev, Usp. Khim. 76, 1084 (2007).

    Article  Google Scholar 

  6. V. V. Kondratiev, N. A. Pogulaichenko, E. G. Tolstopjatova, and V. V. Malev, J. Solid State Electrochem. 15 (11), 2383 (2011).

    Article  Google Scholar 

  7. T. J. Rivers, T. W. Hudson, and C. E. Schmidt, Adv. Func. Mater. 12, 33 (2002).

    Article  Google Scholar 

  8. T. F. Otero, J. G. Martinez, and J. Arias-Pardilla, Electrochim. Acta 84, 112 (2012).

    Article  Google Scholar 

  9. J. Tarver, J. E. Yoo, T. J. Dennes, J. Schwartz, and Y. L. Loo, Chem. Mater. 21, 280 (2009).

    Article  Google Scholar 

  10. V. F. Ivanov, O. L. Gribkova, K. V. Cheberyako, A. A. Nekrasov, V. A. Tverskoi, and A. V. Vannikov, Russ. J. Electrochem. 40 (3), 299 (2004).

    Article  Google Scholar 

  11. S. Bhadra, D. Khastgir, N. K. Singha, and J. H. Lee, Prog. Polym. Sci. 34, 783 (2009).

    Article  Google Scholar 

  12. E. M. Geniés, A. Boyle, M. Lapkowski, and C. Tsintavis, Synth. Met. 36, 139 (1990).

    Article  Google Scholar 

  13. H. J. Niu, M. L. Zhang, W. J. Zang, X. D. Bai, and W. Wang, Mater. Sci. Technol. 18, 796 (2010).

    Google Scholar 

  14. D. D. Borole, U. R. Kapadi, P. P. Mahulikar, and D. G. Hundiwale Mater. Lett. 58 (29), 3816 (2004).

  15. M. I. Florit, J. Electroanal. Chem. 408 (1–2), 257 (1996).

    Article  Google Scholar 

  16. D. D. Borole, U. R. Kapadi, P. P. Mahulikar, and D. G. Hundiwale, Mater. Lett. 60, 2447 (2006).

    Article  Google Scholar 

  17. I. L. Knunyants, Chemical Encyclopedic Dictionary (Sovetskaya Entsiklopediya, Moscow, 1983) [in Russian].

    Google Scholar 

  18. L. F. Tietze and T. Eicher, Reaktionen und Synthesen im organisch-chemischen Praktikum und Forschungslaboratorium (Wiley, Weinheim, 1991, Mir, Moscow, 1999) [in German and in Russian].

    Google Scholar 

  19. I. B. Abdrakhmanov, A. G. Mustafin, and V. M. Sharafutdinov, Claisen Rearrangement in Aromatic Amines (Gilem, Ufa, 2014) [in Russian].

    Google Scholar 

  20. R. B. Salikhov, Yu. N. Biglova, T. R. Salikhov, and Yu.M. Yumaguzin, J. Nanoelectron. Optoelectron. 9 (6), 792 (2015).

    Article  Google Scholar 

  21. R. B. Salikhov, Yu. N. Biglova, Yu. M. Yumaguzin, T. R. Salikhov, M. S. Miftakhov, and A. G. Mustafin, Tech. Phys. Lett. 39 (10), 854 (2013).

    Article  ADS  Google Scholar 

  22. Y. N. Biglova, A. F. Akbylatov, S. A. Torosyan, D. K. Susarova, A. G. Mustafin, and M. S. Miftakhov, Phys. B (Amsterdam, Neth.) 458, 114 (2015).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. B. Salikhov.

Additional information

Original Russian Text © Yu.N. Biglova, R.B. Salikhov, I.B. Abdrakhmanov, T.R. Salikhov, I.N. Safargalin, A.G. Mustafin, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 6, pp. 1228–1233.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Biglova, Y.N., Salikhov, R.B., Abdrakhmanov, I.B. et al. Preparation and investigation of soluble functionalized polyanilines. Phys. Solid State 59, 1253–1259 (2017). https://doi.org/10.1134/S106378341706004X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S106378341706004X

Navigation