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The ionic Seebeck effect and heat of cation transfer in Cu2−δSe superionic conductors

  • Semiconductors and Dielectrics
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Abstract

The ionic Seebeck coefficients of Cu2−δSe superionic conductors are measured in the temperature range 340–380°C. The data obtained are used to determine the heat of transfer Q i of copper ions as a function of the degree of nonstoichiometry and the temperature. The heat of transfer of copper cations increases from 0.19 to 0.22 eV as the degree of nonstoichiometry δ increases from 0.015 to 0.050. It is noted that the heat of transfer Q i tends to increase with an increase in the temperature. Assumptions regarding the specific features of the cation diffusion in the Cu2−δSe superionic conductors are made from the observed closeness of the heat of transfer and the activation energy for ionic conduction.

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Authors and Affiliations

  1. Bashkortostan State University, ul. Frunze 32, Ufa, 450074, Bashkortostan, Russia

    M. Kh. Balapanov, I. B. Zinnurov & G. R. Akmanova

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  1. M. Kh. Balapanov
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  2. I. B. Zinnurov
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  3. G. R. Akmanova
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Original Russian Text © M.Kh. Balapanov, I.B. Zinnurov, G.R. Akmanova, 2006, published in Fizika Tverdogo Tela, 2006, Vol. 48, No. 10, pp. 1762–1765.

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Balapanov, M.K., Zinnurov, I.B. & Akmanova, G.R. The ionic Seebeck effect and heat of cation transfer in Cu2−δSe superionic conductors. Phys. Solid State 48, 1868–1871 (2006). https://doi.org/10.1134/S1063783406100076

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  • DOI: https://doi.org/10.1134/S1063783406100076

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