Abstract
Single crystals and polycrystals of titanium diselenide TiSe2 intercalated with ferrocene Fe(η5-C5H5)2 and cobaltocene Co(η5-C5H5)2 are synthesized. The magnetic susceptibility and electrical resistivity of the intercalation compounds are measured. The results obtained demonstrate that the intercalation brings about the formation of an impurity band with a temperature-dependent width.
Similar content being viewed by others
References
Intercalation Chemistry Ed. by M. S. Whittingham and A. J. Jacobson (Academic, London, 1982).
A. V. Kuranov, V. G. Pleshchev, A. N. Titov, N. V. Baranov, and L. S. Krasavin, Fiz. Tverd. Tela (St. Petersburg) 42(11), 2029 (2000) [Phys. Solid State 42 (11), 2089 (2000)].
F. Cotton and G. Wilkinson, Advanced Inorganic Chemistry (Wiley, New York, 1966; Mir, Moscow, 1969), Vol. 3, p. 162.
R. H. Friend and A. D. Yoffe, Adv. Phys. 36, 1 (1987).
J. S. O. Evans, S. J. Price, H. V. Wong, and D. O’Hare, J. Am. Chem. Soc. 120, 1083 (1998).
R. B. King, Organometallic Syntheses: Transition Metal Compounds (Academic, New York, 1965), Vol. 1.
A. N. Titov, A. V. Kuranov, V. G. Pleschev, Yu. M. Yarmoshenko, M. V. Yablonskikh, A. V. Postnikov, S. Plogmann, M. Neumann, A. V. Ezhov, and E. Z. Kurmaev, Phys. Rev. B: Condens. Matter 63, 035106 (2001).
I. B. Rabinovich, V. P. Nistratov, V. I. Tel’noĭ, and M. S. Sheĭman, Thermodynamics of Organometallic Compounds (Nizhni Novgorod State University, Nizhni Novgorod, 1996), p. 203 [in Russian].
E. M. Shustorovich and M. E. Dyatkina, Zh. Strukt. Khim. 2, 49 (1961).
L. S. Krasavin, A. N. Titov, and V. M. Antropov, Fiz. Tverd. Tela (St. Petersburg) 40(12), 2165 (1998) [Phys. Solid State 40 (12), 1962 (1998)].
J. A. Wilson, Phys. Status Solidi B 86, 11 (1978).
D. O’Hare, W. Jaegerman, D. L. Williamson, F. S. Ohuchi, and B. A. Parkinson, Inorg. Chem. 27, 1537 (1988).
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.N. Titov, O.N. Suvorova, S.Yu. Ketkov, S.G. Titova, A.I. Merentsov, 2006, published in Fizika Tverdogo Tela, 2006, Vol. 48, No. 8, pp. 1385–1389.
Rights and permissions
About this article
Cite this article
Titov, A.N., Suvorova, O.N., Ketkov, S.Y. et al. Synthesis and investigation of titanium diselenide intercalated with ferrocene and cobaltocene. Phys. Solid State 48, 1466–1471 (2006). https://doi.org/10.1134/S1063783406080075
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1063783406080075