Abstract
Antimony (Sb) doped zinc oxide (ZnO) thin films were deposited on the glass substrate at 450°C using spray pyrolysis technique. Effect of Sb doping on surface morphology structural, optical and electrical properties were studied. X-ray diffraction (XRD) analysis showed that both the undoped and doped ZnO thin films are polycrystalline in nature with (101) preferred orientation. SEM analysis showed a change in surface morphology of Sb doped ZnO thin films. Doping results in a marked increase in conductivity without affecting the transmittance of the films. ZnO films prepared with 3 at % Sb shows the lowest resistivity of 0.185 Ohm cm with a Hall mobility of 54.05 cm2 V–1 s–1, and a hole concentration of 6.25 × 1017 cm–3.
Similar content being viewed by others
References
D. C. Look, Mater. Sci. Eng. B 80, 383 (2001).
M. H. Haung, S. Mao, and H. Feick, Science 292, 1899 (2001).
Sang Yeol Lee, Eun Sub Shim, Hong Seong Kang, Seong Sik Pang, and Jeong Seok Kang, Thin Solid Films 473, 34 (2005).
R. Maity, A. N. Banerjee, and K. K. Chattopadhyay, Appl. Surf. Sci. 236, 231 (2004).
S. Fay, J. Steinhauser, N. Oliveira, E. Vallat-Sauvain, and C. Ballif, Thin Solid Films 515, 8558 (2007).
Young Ran Park, Eung Kwon Kim, Donggeun Jung, Tae Seok Park, and Young Sung Kim, Appl. Surf. Sci. 254, 2250 (2008).
Li Gong, Zhizhen Ye, Jianguo Lu, Liping Zhu, Jingyun Huang, Xiuquan Gu, and Binghui Zhao, Vacuum 84, 947 (2010).
H. J. Lim, D. Yong, and Y. J. Oha, Sens. Actuators A 125, 405 (2006).
M. Miki-Yoshida, V. Collins-Martinez, P. AmezagaMadrid, and A. Aguilar-Elguezabal, Thin Solid Films 419, 60 (2002).
Chien-Yie Tsaya, Kai-Shiung Fana, Sih-Han Chena, and Chia-Hao Tsai, J. Alloys Comp. 495, 126 (2010).
Chae-Seon Hong, Hyeong-Ho Park, Jooho Moon, and Hyung-Ho Park, Thin Solid Films 515, 957 (2006).
Amit Kumar, Manoj Kumar, and Beer Pal Singh, Appl. Surf. Sci. 256, 7200 (2010).
Soumen Dhara and P. K. Giri, Thin Solid Films 520, 5000 (2012).
B. L. Zhu, C. S. Xie, J. Wu, D. W. Zeng, A. H. Wang, and X. Z. Zhao, Mater. Chem. Phys. 96, 459 (2006).
Xinhua Pan Zhizhen Ye, Jiesheng Li, Xiuquan Gu, Yujia Zeng, Haiping He, Liping Zhu, and Yong Che, Appl. Surf. Sci. 253, 5067 (2007).
T. Yang, B. Yao, T. T. Zhao, G. Z. Xing, H. Wang, H. L. Pan, R. Deng, Y. R. Sui, L. L. Gao, H. Z. Wang, T. Wuc, and D. Z. Shen, J. Alloys Comp. 509, 5426 (2011).
G. Jimenez-Cadena, E. Comini, M. Ferroni, A. Vomiero, and G. Sberveglieri, Mater. Chem. Phys. 124, 694 (2010).
Min Su Kim, Do Yeob Kim, Min Young Cho, Giwoong Nam, Soaram Kim, Dong-Yul Lee, Sung-O Kim, and Jae-Young Leem, Vacuum 86, 1373 (2012).
Xuan Fang, Jinhua Li, Dongxu Zhao, Binghui Li, Zhenzhong Zhang, Dezhen Shen, Xiaohua Wang, and Zhipeng Wei, Thin Solid Films 518, 5687 (2010).
Q. J. Feng, L. Z. Hub, H. W. Liang, Y. Feng, J. Wang, J. C. Sun, J. Z. Zhao, M. K. Li, and L. Dong, Appl. Surf. Sci. 257, 1084 (2010).
H. Benelmadjat, N. Touka, B. Harieche, B. Boudine, O. Halimi, and M. Sebais, Opt. Mater. 32, 764 (2010).
T. V. Vimalkumar, N. Poornima, K. B. Jinesh, C. Sudha Kartha, and K. P. Vijayakumar, Appl. Surf. Sci. 257, 8334 (2011).
W. W. Zhong, F. M. Liu, L. G. Cai, C. C. Zhou, P. Ding, and H. Zhang, J. Alloys Comp. 499, 265 (2010).
M. Rusop, K. Uma, T. Soga, and T. Jimbo, Mater. Sci. Eng. B 127, 150 (2006).
T. Prasada Rao and M. C. Santhoshkumar, Appl. Surf. Sci. 255, 4579 (2009).
U. Alver, T. K l nc, E. Bacaks z,_T. Kucukomeroglu, S. Nezir, I. H. Mutlu, and F. Aslan, Thin Solid Films 515, 3448 (2007).
Anubha Jain,_P. Sagar, and R. M. Mehra, Solid State Electron. 50, 1420 (2006).
F. Chouikh, Y. Beggah, and M. S. Aida, J. Mater. Sci.: Mater. Electron. 22, 499 (2011).
Yasemin Caglar, Saliha Ilican, Mujdat Caglar, and Fahrettin Yakuphanoglu, Spectrochim. Acta A 67, 1113 (2007).
B. L. Zhu, C. S. Xie, J. Wu, D. W. Zeng, A. H. Wang, and X. Z. Zhao, Mater. Chem. Phys. 96, 459 (2006).
Xinhua Pan, Zhizhen Ye, Jiesheng Li, Xiuquan Gu, Yujia Zeng, Haiping He, Liping Zhu, and Yong Che, Appl. Surf. Sci. 253, 5067 (2007).
K. Samanta, A. K. Arora, S. Hussain, S. Chakravarty, and R. S. Katiyar, Curr. Appl. Phys. 12, 1381 (2012).
S. Limpijumnong, S. B. Zhang, S. H. Wei, and C. H. Park, Phys. Rev. Lett. 92, 155504 (2004).
A. E. Jimenez-Gonzalez, J. A. Soto Urueta, and R. Suarez-Parra, J. Cryst. Growth 192, 430 (1998).
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Sadananda Kumar, N., Bangera, K.V. & Shivakumar, G.K. Properties of antimony doped ZnO thin films deposited by spray pyrolysis technique. Semiconductors 49, 899–904 (2015). https://doi.org/10.1134/S1063782615070143
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063782615070143